Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Methyl nicotinate(93-60-7)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Methyl nicotinate
Synonyms
3-(Carbomethoxy)pyridine
3-(Methoxycarbonyl)pyridine
m-(Methoxycarbonyl)pyridine
Methyl 3-pyridinecarboxylate
Nicometh
Nicotinic acid, methyl ester
CAS
93-60-7
Formula
C7H7NO2
Molecular Weight
137.13999999999999
EINECS
202-261-8
RTECS
QT1925000
RTECS Class
Other
Merck
12,6174
Beilstein/Gmelin
113951
Beilstein Reference
5-22-02-00059
EC Class
irritant, sensitizing

Physical and Chemical Properties

Appearance
White solid.
Solubility in water
Soluble
Melting Point
39
Boiling Point
209
Vapor Pressure
3.0 (25 C)
Density
1.0048 g/cm3 (20 C)
pKa/pKb
10.81 (pKb)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation
Remove from exposure to fresh air immediately. Get medical aid if cough or other symptoms appear.
Skin
Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification

Ingestion
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Skin
May cause skin irritation. May cause reddening of the skin.
Eyes
May cause eye irritation.
EC Risk Phrase
R 36/37/38
EC Safety Phrase
S 26 36

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Poison Class
4

Fire Fighting Measures

Flash Point
95
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Use agent most appropriate to extinguish fire.

Accidental Release Measures

Small spills/leaks
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions.

Stability and Reactivity

Disposal Code
3
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents - strong bases.
Decomposition
Nitrogen oxides, carbon monoxide, carbon dioxide.

Transport Information

HS Code
2933 39 99
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