Home > Fluorocarbon 11 > Fluorocarbon 11(75-69-4)
Fluorocarbon 11(75-69-4)
Supplier Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Transport Information
Product Identification
Product Name
Fluorocarbon 11
Fluorocarbon 11
Synonyms
Butaneperoxoic acid, 2-ethyl-, 1,1-dimethylethyl ester
Fluorotrichloromethane
R 11
tert-Butyl 2-ethylperoxybutyrate
tert-Butyl perdiethylacetate
tert-Butyl peroxy-2-ethylbutyrate
Trichloromonofluoromethane
Trigonox 27
Butaneperoxoic acid, 2-ethyl-, 1,1-dimethylethyl ester
Fluorotrichloromethane
R 11
tert-Butyl 2-ethylperoxybutyrate
tert-Butyl perdiethylacetate
tert-Butyl peroxy-2-ethylbutyrate
Trichloromonofluoromethane
Trigonox 27
CAS
2550-33-6
2550-33-6
CAS
75-69-4
75-69-4
Formula
C10H20O3
C10H20O3
Formula
CCl3F
CCl3F
Molecular Weight
137.37
137.37
Molecular Weight
188.27
188.27
EINECS
200-892-3
200-892-3
EINECS
219-850-0
219-850-0
RTECS
PB6125000
PB6125000
RTECS Class
Tumorigen; Human Data
Tumorigen; Human Data
Merck
12,9770
12,9770
Beilstein/Gmelin
2637996
2637996
Beilstein/Gmelin
1732469
1732469
Beilstein Reference
4-01-00-00054
4-01-00-00054
Physical and Chemical Properties
Appearance
A clear light colored liquid. Nearly odorless.
A clear light colored liquid. Nearly odorless.
Solubility in water
Insoluble
Insoluble
Solubility in water
1 g/L
1 g/L
Melting Point
-111.1
-111.1
Melting Point
31
31
Boiling Point
23.8
23.8
Boiling Point
249
249
Vapor Pressure
665 (20 C)
665 (20 C)
Density
1.4995 g/cm3 (15 C)
1.4995 g/cm3 (15 C)
Partition Coefficient
2.53
2.53
Partition Coefficient
1.47
1.47
Heat Of Vaporization
25.1 kj/mol
25.1 kj/mol
Usage
Substance is used in refrigeration machinery requiring a refrigerant effective at negative pressures.
Substance is used in refrigeration machinery requiring a refrigerant effective at negative pressures.
Vapor Density
>1
>1
Refractive Index
1.3865 (20 C)
1.3865 (20 C)
Refractive Index
1.4198 (20 C)
1.4198 (20 C)
First Aid Measures
Ingestion
DO NOT INDUCE VOMITING. Volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital.
DO NOT INDUCE VOMITING. Volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital.
Ingestion
Seek medical assistance.
Seek medical assistance.
Inhalation
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
Inhalation
May cause severe injury or burns.
May cause severe injury or burns.
Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
Skin
See Inhalation.
See Inhalation.
Skin
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
Skin
Remove and isolate contaminated clothing and shoes. Remove material from skin immediately. Immediately flush with running water for at least 20 minutes.
Remove and isolate contaminated clothing and shoes. Remove material from skin immediately. Immediately flush with running water for at least 20 minutes.
Eyes
See Inhalation.
See Inhalation.
Eyes
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Eyes
Immediately flush with running water for at least 20 minutes.
Immediately flush with running water for at least 20 minutes.
Handling and Storage
Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Storage
Store at room temperature. Venting: safety relief
Store at room temperature. Venting: safety relief
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Handling
Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.
Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.
Hazards Identification
Ingestion
See Inhalation.
See Inhalation.
Inhalation
Vapors may cause dizziness or asphyxiation without warning.
Vapors may cause dizziness or asphyxiation without warning.
Skin
Dermal contact may result in defatting, irritation or contact dermatitis. Severe frostbite has been reported as an effect of freon exposure. Injection causes transient pain, erythema and edema.
Dermal contact may result in defatting, irritation or contact dermatitis. Severe frostbite has been reported as an effect of freon exposure. Injection causes transient pain, erythema and edema.
Eyes
See Skin.
See Skin.
Ingestion
Nausea may develop. Ingestion of a small amount of trichlorofluoromethane resulted in necrosis and perforation of the stomach in one patient.
Nausea may develop. Ingestion of a small amount of trichlorofluoromethane resulted in necrosis and perforation of the stomach in one patient.
Hazards
Vapors from liquefied gas are initially heavier than air and spread along ground.
Vapors from liquefied gas are initially heavier than air and spread along ground.
Hazards
May ignite combustibles (wood, paper, oil, clothing, etc.). May ignite spontaneously if exposed to air. May be ignited by heat, sparks or flames.
May ignite combustibles (wood, paper, oil, clothing, etc.). May ignite spontaneously if exposed to air. May be ignited by heat, sparks or flames.
UN (DOT)
2144
2144
UN (DOT)
2599
2599
Exposure Controls/Personal Protection
Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Wear positive pressure self-contained breathing apparatus (SCBA).
Exposure Effects
Headache, dizziness, and disorientation are common. Cerebral edema may be found on autopsy. Dichlorodifluoromethane was not teratogenic in rats and rabbits. <br>The reproductive effects of 1,1,1,2-tetrafluoroethane were studied in rats. No adverse effects on reproductive performance was noted or on the development, maturation or reproductive performance of up to two successive generations.
Headache, dizziness, and disorientation are common. Cerebral edema may be found on autopsy. Dichlorodifluoromethane was not teratogenic in rats and rabbits. <br>The reproductive effects of 1,1,1,2-tetrafluoroethane were studied in rats. No adverse effects on reproductive performance was noted or on the development, maturation or reproductive performance of up to two successive generations.
Exposure limit(s)
OSHA PEL: TWA 1000 ppm (5600 mg/m3) NIOSH REL: C 1000 ppm (5600 mg/m3) NIOSH IDLH: 2000 ppm
OSHA PEL: TWA 1000 ppm (5600 mg/m3) NIOSH REL: C 1000 ppm (5600 mg/m3) NIOSH IDLH: 2000 ppm
Poison Class
5
5
Fire Fighting Measures
Fire Fighting
Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Keep run-off water out of sewers and water sources.
Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Keep run-off water out of sewers and water sources.
Fire Fighting
The temperature of the substance must be maintained at or below the Control Temperature at all times. Small Fires: Water spray or fog is preferred; if water not available use dry chemical, carbon dioxide or regular foam. Large Fires: Flood fire area with water from a distance. Use water spray or fog; do not use straight streams.
The temperature of the substance must be maintained at or below the Control Temperature at all times. Small Fires: Water spray or fog is preferred; if water not available use dry chemical, carbon dioxide or regular foam. Large Fires: Flood fire area with water from a distance. Use water spray or fog; do not use straight streams.
Fire Potential
May burn but does not ignite readily
May burn but does not ignite readily
Fire Potential
May explode from heat, contamination or loss of temperature control. Particularly sensitive to temperature rises.
May explode from heat, contamination or loss of temperature control. Particularly sensitive to temperature rises.
Accidental Release Measures
Small spills/leaks
ELIMINATE all ignition sources and combustible materials. Do not touch spilled material. Stop leak if you can do it without risk. Take up with inert, damp, noncombustible material using clean non-sparking tools and place into loosely covered plastic containers for later disposal. For large spills, contact specialist for clean-up or disposal instructions.
ELIMINATE all ignition sources and combustible materials. Do not touch spilled material. Stop leak if you can do it without risk. Take up with inert, damp, noncombustible material using clean non-sparking tools and place into loosely covered plastic containers for later disposal. For large spills, contact specialist for clean-up or disposal instructions.
Small spills/leaks
Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Apply water spray or mist to knock down vapors. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commercial sorbents. Water spill: Use natural barriers or oil spill control booms to limit spill travel. Remove trapped material with suction hoses.
Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Apply water spray or mist to knock down vapors. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commercial sorbents. Water spill: Use natural barriers or oil spill control booms to limit spill travel. Remove trapped material with suction hoses.
Stability and Reactivity
Incompatibilities
Incompatible with alkali or alkaline earth metals, powdered aluminum, zinc and beryllium Reacts violently with barium and lithium.
Incompatible with alkali or alkaline earth metals, powdered aluminum, zinc and beryllium Reacts violently with barium and lithium.
Stability
No data.
No data.
Stability
Stable.
Stable.
Decomposition
Hydrogen chloride, hydrogen fluoride, phosgene.
Hydrogen chloride, hydrogen fluoride, phosgene.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.
Fire may produce irritating, corrosive and/or toxic gases.
Combustion Products
Produces irritating and toxic products when heated to decomposition temperatures.
Produces irritating and toxic products when heated to decomposition temperatures.
Transport Information
UN Number
2144
2144
UN Number
2599
2599
Hazard Class
5.2
5.2
Hazard Class
2.2
2.2
Contact
More
- Company Name:BEST-REAGENT
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- Company Name:Chengdu HuaXia Chemical Reagent Co. Ltd
- Tel:400-1166-196 13458535857
- Fax:QQ：800101999
- WebSite:http://www.hx-r.com
- Company Name:Chengdu Dianchun Technology Co., Ltd
- Tel:400-1166-196 18502815961
- Fax:QQ：800101999
- WebSite:http://www.hx-r.com