Home > 2-Bromopropionic acid methyl ester > 2-Bromopropionic acid methyl ester(5445-17-0)
2-Bromopropionic acid methyl ester(5445-17-0)
Supplier Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Transport Information
Product Identification
Product Name
2-Bromopropionic acid methyl ester
2-Bromopropionic acid methyl ester
Synonyms
Methyl DL-2-bromopropanoate
Propanoic acid, 2-bromo-, methyl ester
Propionic acid, 2-bromo-, methyl ester
Methyl DL-2-bromopropanoate
Propanoic acid, 2-bromo-, methyl ester
Propionic acid, 2-bromo-, methyl ester
CAS
5445-17-0
5445-17-0
Formula
C4H7BrO2
C4H7BrO2
Molecular Weight
167.01
167.01
EINECS
226-642-3
226-642-3
Beilstein/Gmelin
1720592
1720592
Beilstein Reference
4-02-00-00762
4-02-00-00762
EC Class
flammable, irritant
flammable, irritant
Physical and Chemical Properties
Appearance
Clear, colorless liquid.
Clear, colorless liquid.
Solubility in water
Slightly soluble
Slightly soluble
Boiling Point
51
51
Density
1.5 g/cm3 (15 C)
1.5 g/cm3 (15 C)
Vapor Density
5.76
5.76
Refractive Index
1.45 (20 C)
1.45 (20 C)
First Aid Measures
Ingestion
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.
Handling and Storage
Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Handling
Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Use only in a chemical fume hood. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapors.
Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Use only in a chemical fume hood. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapors.
Hazards Identification
Inhalation
Causes respiratory tract irritation. Vapors may cause dizziness or suffocation. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Can produce delayed pulmonary edema.
Causes respiratory tract irritation. Vapors may cause dizziness or suffocation. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Can produce delayed pulmonary edema.
Skin
Causes severe skin irritation and possible burns. May cause cyanosis of the extremities.
Causes severe skin irritation and possible burns. May cause cyanosis of the extremities.
Eyes
Lachrymator. Causes severe eye irritation and possible burns. May cause chemical conjunctivitis and corneal damage.
Lachrymator. Causes severe eye irritation and possible burns. May cause chemical conjunctivitis and corneal damage.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression.
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
EC Risk Phrase
R 10 34 36
R 10 34 36
EC Safety Phrase
S 26 36/37/39 45
S 26 36/37/39 45
UN (DOT)
1993
1993
Exposure Controls/Personal Protection
Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Exposure Effects
Effects may be delayed.
Effects may be delayed.
Fire Fighting Measures
Flash Point
53
53
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam.
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam.
Fire Potential
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Accidental Release Measures
Small spills/leaks
Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Stability and Reactivity
Disposal Code
2
2
Incompatibilities
Acids, bases, oxidizing agents, reducing agents.
Acids, bases, oxidizing agents, reducing agents.
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Stable at room temperature in closed containers under normal storage and handling conditions.
Decomposition
Carbon monoxide, carbon dioxide, hydrogen bromide.
Carbon monoxide, carbon dioxide, hydrogen bromide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.
Fire may produce irritating, corrosive and/or toxic gases.
Transport Information
UN Number
1993
1993
Hazard Class
3
3
Packing Group
I; II; III
I; II; III
HS Code
2915 90 80
2915 90 80
Contact
More
- Company Name:Wuhan Yuqing Jiaheng Pharmaceutical Co., Ltd.
- Tel:027-83850122 13343472658
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- Company Name:J & K SCIENTIFIC LTD.
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- Fax:86-10-82849933
- WebSite:http://www.jkchemical.com
- Company Name:Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel:021-61259108 18621169085
- Fax:86-21-61259102
- WebSite:https://www.meryer.com/cn/index/
- Company Name:Alfa Aesar
- Tel:400-6106006
- Fax:021-67582001/03/05
- WebSite:http://chemicals.thermofisher.cn
- Company Name:TCI (Shanghai) Development Co., Ltd.
- Tel:021-67121386
- Fax:021-67121385
- WebSite:https://www.tcichemicals.com/CN/zh/