Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Acetophenone oxime(613-91-2)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Acetophenone oxime
Synonyms
(NE)-N-(1-Phenylethylidene)hydroxylamine
1-Phenylethanone oxime
CAS
613-91-2
Formula
C8H9NO
Molecular Weight
135.16
EINECS
210-360-2
RTECS
AM9654000
RTECS Class
Drug
Beilstein/Gmelin
1562059
Beilstein Reference
3-07-00-00954

Physical and Chemical Properties

Appearance
Solid.
Solubility in water
Slightly soluble
Melting Point
58 - 60
Boiling Point
245
Vapor Pressure
0.02 (25 C)
Density
1.0515 g/cm3 (78 C)
pKa/pKb
11.39 (pKa)
Partition Coefficient
1.66
Heat Of Vaporization
50.9 kJ/mol
Refractive Index
1.547 (78 C)

First Aid Measures

Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Store in a cool, dry place. Keep container closed when not in use. Refrigerator (approx 4 C).
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Do not ingest or inhale.

Hazards Identification

Ingestion
Harmful if swallowed. Ingestion of large amounts may cause gastrointestinal irritation.
Inhalation
May cause respiratory tract irritation.
Skin
May cause skin irritation.
Eyes
May cause eye irritation.
EC Risk Phrase
R 22
EC Safety Phrase
S 22 36/37

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point
138
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Accidental Release Measures

Small spills/leaks
Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal.

Stability and Reactivity

Disposal Code
3
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, moisture, acids, metals, and alkali.
Decomposition
Irritating and toxic fumes and gases.

Transport Information

HS Code
2928 00 90
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