Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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3-Pyridinecarboxylic acid(59-67-6)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
3-Pyridinecarboxylic acid
Synonyms
3-Pyridinecarboxylic acid
Niacin
Vitamin B3
CAS
59-67-6
Formula
C6H5NO2
Molecular Weight
123.11
EINECS
200-441-0
RTECS
QT0525000
RTECS Class
Drug; Human Data
Merck
12,6612
Beilstein/Gmelin
109591
Beilstein Reference
5-22-02-00057
EC Class
irritant

Physical and Chemical Properties

Appearance
Odorless white crystalline powder with a feebly acid taste.
Solubility in water
17 g/L
Melting Point
142
Boiling Point
258
Vapor Pressure
0.00084 (25 C)
Density
1.473 g/cm3 (20 C)
pKa/pKb
2.17 (pKa)
Partition Coefficient
.36
Heat Of Vaporization
Heat Of Combustion
-2731 kJ/mol
Usage
One of the b vitamins.
Vapor Density
4.25
Refractive Index
1.4936

First Aid Measures

Ingestion
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Skin
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Store in a cool, dry place. Store in a tightly closed container.
Handling
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Keep container tightly closed. Use only in a chemical fume hood.

Hazards Identification

Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Skin
May cause skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis. The toxicological properties of this material have not been fully investigated.
Eyes
May cause eye irritation.
EC Risk Phrase
R 36
EC Safety Phrase
S 26 36

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.
Exposure limit(s)
OEL-RUSSIA:STEL 1 mg/m3
Poison Class
4

Fire Fighting Measures

Flash Point
131
Autoignition
> 365
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam. Use agent most appropriate to extinguish fire.
Fire Potential
This material is probably combustible.

Accidental Release Measures

Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Transport Information

HS Code
2936 29 90
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