Supplier Product Identification Physical and Chemical Properties First Aid Measures Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Transport Information Stability and Reactivity
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2-Toluenesulfonyl isocyanate(32324-19-9)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Transport Information Stability and Reactivity

Product Identification

Product Name
2-Toluenesulfonyl isocyanate
Synonyms
2-Methyl-N-(oxomethylidene)benzenesulfonamide
CAS
32324-19-9
Formula
C8H7NO3S
Molecular Weight
197.21
Beilstein/Gmelin
2836885

Physical and Chemical Properties

Boiling Point
87 - 89 (.08 torr)
Density
1.303 g/cm3 (20 C)
Refractive Index
1.54 (20 C)

First Aid Measures

Ingestion
Seek medical assistance.
Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
Skin
Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin.
Eyes
Immediately flush with running water for at least 20 minutes.

Hazards Identification

Ingestion
See Inhalation.
Inhalation
TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns, or death. Effects may be delayed.
Skin
See Inhalation.
Eyes
See Inhalation.
Hazards
Vapors form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff.
EC Risk Phrase
R 14 36/37/38 42
EC Safety Phrase
S 23 26 36/37/39 45
UN (DOT)
2206

Exposure Controls/Personal Protection

Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).

Fire Fighting Measures

Flash Point
>110
Fire Fighting
Note: Most foams will react with the material and release corrosive/toxic gases. Small Fires: carbon dioxide, dry chemical, dry sand, alcohol-resistant foam. Large Fires: Water spray, fog or alcohol-resistant foam.
Fire Potential
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Accidental Release Measures

Small spills/leaks
ELIMINATE all ignition sources and groumd all equipment used when handling the product. Do not touch spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce vapors. DO NOT GET WATER on spilled substance or inside containers. Cover with DRY earth, DRY sand, or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean non-sparking tools to collect material and place it into loosley covered plastic containers for later disposal.

Transport Information

UN Number
2206

Stability and Reactivity

Combustion Products
Fire will produce irritating, corrosive and/or toxic gases.
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