3-Chloro-4-fluorothiophenol

EMERGENCY OVERVIEW 
Irritating to eyes, respiratory system and skin. 
Potential Health Effects 
Eye: 
Causes eye irritation. May cause chemical conjunctivitis. 
Skin: 
Causes skin irritation. 
Ingestion: 
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. 
Inhalation: 
Causes respiratory tract irritation. Can produce delayed pulmonary edema. 
Chronic: 
Effects may be delayed. 

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Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. 
Skin: 
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. 
Ingestion: 
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. 
Inhalation: 
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. 
Notes to Physician: 
Treat symptomatically and supportively. 

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Section 5 - FIRE FIGHTING MEASURES
General Information: 
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Runoff from fire control or dilution water may cause pollution. 
Extinguishing Media: 
Use water spray, dry chemical, carbon dioxide, or chemical foam. 

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8. 
Spills/Leaks: 
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. 

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Section 7 - HANDLING and STORAGE
Handling: 
Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse. 
Storage: 
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. 

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls: 
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. 
Exposure Limits CAS# 60811-23-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. 
Skin: 
Wear appropriate protective gloves to prevent skin exposure. 
Clothing: 
Wear appropriate protective clothing to prevent skin exposure. 
Respirators: 
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. 

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid 
Color: Not available. 
Odor: stench 
pH: Not available. 
Vapor Pressure: Not available. 
Viscosity: Not available. 
Boiling Point: 68-70 deg C@2 mmHg 
Freezing/Melting Point: Not available. 
Autoignition Temperature: Not available. 
Flash Point: Not available. 
Explosion Limits, lower: Not available. 
Explosion Limits, upper: Not available. 
Decomposition Temperature: 
Solubility in water: 
Specific Gravity/Density: 
Molecular Formula: C6H4ClFS 
Molecular Weight: 162.61 

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability: 
Stable at room temperature in closed containers under normal storage and handling conditions. 
Conditions to Avoid: 
Incompatible materials, excess heat. 
Incompatibilities with Other Materials: 
Oxidizing agents, strong bases. 
Hazardous Decomposition Products: 
Hydrogen chloride, sulfur dioxide, carbon monoxide, carbon dioxide, hydrogen fluoride gas, sulfuric acid. 
Hazardous Polymerization: Has not been reported 

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#: 
CAS# 60811-23-6 unlisted. 
LD50/LC50: 
Not available. 
Carcinogenicity: 
3-Chloro-4-fluorothiophenol - Not listed by ACGIH, IARC, or NTP. 

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Section 12 - ECOLOGICAL INFORMATION
 

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations. 

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Section 14 - TRANSPORT INFORMATION

IATA 
Shipping Name: Not regulated. 
Hazard Class: 
UN Number: 
Packing Group: 
IMO 
Shipping Name: Not regulated. 
Hazard Class: 
UN Number: 
Packing Group: 
RID/ADR 
Not regulated as a hazardous material. 

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Section 15 - REGULATORY INFORMATION

European/International Regulations 
European Labeling in Accordance with EC Directives 
Hazard Symbols: XI 
Risk Phrases: 
R 36/37/38 Irritating to eyes, respiratory system 
and skin. 
Safety Phrases: 
S 26 In case of contact with eyes, rinse immediately 
with plenty of water and seek medical advice. 
S 37/39 Wear suitable gloves and eye/face 
protection. 
WGK (Water Danger/Protection) 
CAS# 60811-23-6: No information available. 
Canada 
None of the chemicals in this product are listed on the DSL/NDSL list. 
CAS# 60811-23-6 is not listed on Canada's Ingredient Disclosure List. 
US FEDERAL 
TSCA 
CAS# 60811-23-6 is not listed on the TSCA inventory. 
It is for research and development use only. 
 

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SECTION 16 - ADDITIONAL INFORMATION
N/A