(TRIMETHYLSILYL)DIAZOMETHANE

$ 1.00 /1KG

Min. Order1G
Purity99%
Cas No18107-18-1
Supply Ability100kg
Update time2019-07-06

career henan chemical co

7YR

China

Chemical Properties

Product Name	(TRIMETHYLSILYL)DIAZOMETHANE
CAS No	18107-18-1
EC-No
Min. Order	1G
Purity	99%
Supply Ability	100kg
Release date	2019/07/06

AD68

(TRIMETHYLSILYL)DIAZOMETHANE Basic information

Product Name:	(TRIMETHYLSILYL)DIAZOMETHANE
Synonyms:	(trimethylsilyl)diazomethanesolution;(DIAZOMETHYL)TRIMETHYLSILANE;TMS-DIAZOMETHANE;(TRIMETHYLSILYL)DIAZOMETHANE;(TRIMETHYLSILYL)DIAZOMETHANE, 2.0 M IN D;(TRIMETHYLSILYL)DIAZOMETHANE, 2.0M SOLUT ION IN HEXANES;(TRIMETHYLSILYL)DIAZOMETHANE SOLUTION, ~2 M IN HEXANE;Trimethylsilyldiazomethane2.0MINdiethylester
CAS:	18107-18-1
MF:	C4H10N2Si
MW:	114.22
EINECS:
Product Categories:	Analytical Chemistry;Diazomethane Precursors & Equivalents (GC Derivatizing Reagents);Esterification & Alkylation (GC Derivatizing Reagents);GC Derivatizing Reagents;Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry
Mol File:	18107-18-1.mol

(TRIMETHYLSILYL)DIAZOMETHANE Chemical Properties

Boiling point	96 °C
density	0.773 g/mL at 25 °C
refractive index	1.4362
Fp	−31 °F
storage temp.	Refrigerator
form	Solution
color	White
Water Solubility	Immiscible with water. Miscible with organic solvents.
Sensitive	Moisture & Light Sensitive
BRN	1902903
CAS DataBase Reference	18107-18-1(CAS DataBase Reference)

Safety Information

Hazard Codes	F+,Xn,N,F,T,T+
Risk Statements	12-19-22-66-67-65-62-51/53-48/20-38-11-23-39/26-26-45
Safety Statements	9-16-29-33-36/37-61-62-45-28-53
RIDADR	UN 1208 3/PG 2
WGK Germany	3
F	10
TSCA	Yes
HazardClass	3
PackingGroup	II

(TRIMETHYLSILYL)DIAZOMETHANE Usage And Synthesis

Chemical Properties

clear yellow solution

Uses

Reactant for preparation of: &bull Macrolactam analogs of the natural product macrolide (-)-A26771B with improved metabolic stability and antibacterial activity &bull Aigialomycin D analogues as protein kinase inhibitors for cancer treatment &bull Unnatural α-amino acid derivatives containing gem-bisphosphonates via Michael addition reaction &bull Capped 4-methylumbelliferyl hyaluronan disaccharides and tetrasaccharides as potential hyaluronidase substrates &bull Stictamides A-C as matrix metallopeptidase 12 (MMP12) inhibitors with antitumor invasion activity &bull Endothelin converting enzyme (ECE) Inhibitors WS 75624A and WS 75624B via a cross-metathesis approach &bull Ent-kaurene derivatives as anti-inflammatory agents &bull Desmosdumotin C analogs as potent antitumor agents acting via activation of spindle assembly checkpoint &bull Imidazolo[2,1-b]benzothiazole derivatives as potential p53 inhibitors

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