1,1'-Bis(diphenylphosphino)ferrocene

$ 1.00 /1KG

career henan chemical co

7YR

China

Chemical Properties

Product Name	1,1'-Bis(diphenylphosphino)ferrocene
CAS No	12150-46-8
EC-No	430-420-3
Min. Order	1KG
Purity	99%
Supply Ability	1000KG
Release date	2019/07/06

AD68

1,1'-Bis(diphenylphosphino)ferrocene Basic information

Reaction

Product Name:	1,1'-Bis(diphenylphosphino)ferrocene
Synonyms:	DPPF;1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE;1,1'-FERROCENEDIYL-BIS(DIPHENYLPHOSPHINE);1,1'-FERROCENEBIS(DIPHENYLPHOSPHINE);1,1'-bis(diphenyphosphino)ferrocene;1,1'-bis(diphenyphosphino)ferrocene(dppf);1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, 97 %;1,1'-Bis(diphenylphosphino)ferrocene,99%DPPF
CAS:	12150-46-8
MF:	C34H28FeP2 10*
MW:	554.38
EINECS:	430-420-3
Product Categories:	Phosphines;Boron, Nitrile, Thio,& TM-Cpds;Miscellaneous;pharmacetical;Ligand;Catalysts-Ligands;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Metallocenes;Phosphine Ligands;Synthetic Organic Chemistry;Transition Metal Compounds;Aromatics;Catalyst;Chelating Agents & Ligands;Pharmaceutical intermediates;Achiral Phosphine;Aryl Phosphine
Mol File:	12150-46-8.mol

1,1'-Bis(diphenylphosphino)ferrocene Chemical Properties

Melting point	181-182 °C (dec.)(lit.)
storage temp.	2-8°C
form	crystal
color	yellow to orange
Water Solubility	Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
Sensitive	Air Sensitive
Stability:	Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference	12150-46-8(CAS DataBase Reference)
NIST Chemistry Reference	1,1'-Bis(diphenylphosphino)ferrocene(12150-46-8)

Safety Information

1,1'-Bis(diphenylphosphino)ferrocene Usage And Synthesis

Reaction	Ligand for Pd-catalyzed cross-coupling. Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures. Ligand for Ni-catalyzed amination of aryl chlorides. Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles. Ligand for Ni-catalyzed Suzuki reactions. Ni-catalyzed hydroamination of 1,3-dienes. Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene. Pd-catalyzed γ-arylation of β,γ-unsaturated ketones. Ligand for Ru-catalyzed reduction of nitriles to primary amines. Ligand for Rh-catalyzed alkyne head-to-tail dimerization. Ligand for Rh-catalyzed cross-coupling Ligand for Rh-catalyzed olefin isomerization Ligand for Ni or Rh-catalyzed borylation Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes.
Chemical Properties	deep yellow crystalline powder
Uses	suzuki reaction
Uses	Commonly used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which i s a popular reagent for palladium-catalyzed coupling reactions.

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