The 85.8 parts of4-Methylbenzene-1,3-diamine , 42 parts of4-(4-Aminophenyl)benzenamine, 36 parts of M-nitroaniline and 600 parts of mixture of sulfur in the 220 ~ 240 ℃ calcination 9 hours, in Sodium sulfide solution treatment its product, and acid precipitation (BIOS1155,37). With 4-Aminophenol instead of M-nitroanilineget similar dye.