The 85.8 parts of?4-Methylbenzene-1,3-diamine , 42 parts of?4-(4-Aminophenyl)benzenamine, 36 parts of ?M-nitroaniline and 600 parts of ?mixture of sulfur in the 220 ~ 240 ℃ calcination 9 hours, in Sodium sulfide solution treatment its product, and acid precipitation (BIOS?1155,37). With 4-Aminophenol instead of M-nitroaniline?get similar dye.