1-Amino-2-hydroxynaphthalene-6-sulfonic acid [5639-34-9]. (5-amino-6-hydroxynaphthalene-2-sulfonic acid), amino-Schaeffer acid, C10H9NO4S, Mr 239.2, is obtained as needles or prisms that are only slightly soluble in boiling water. The sodium salt is soluble in water but can be isolated as the hemipentahydrate. Diazotization does not occur in mineral acid medium. The diazo oxide is formed by reaction with sodium nitrite in the presence of copper(II) sulfate.