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Nitrogen Tetroxide

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dinitrogen tetroxide: A colourlessto pale yellow liquid or a brown gas,N<sub>2</sub>O<sub>4</sub>; r.d. 1.45 (liquid); m.p. –11.2°C;b.p. 21.2°C. It dissolves in water withreaction to give a mixture of nitricacid and nitrous acid. It may be readilyprepared in the laboratory by thereaction of copper with concentratednitric acid; mixed nitrogen oxidescontaining dinitrogen oxide may alsobe produced by heating metal nitrates.The solid compound is whollyN<sub>2</sub>O<sub>4</sub> and the liquid is about 99%N<sub>2</sub>O<sub>4</sub> at the boiling point; N2O4 is diamagnetic.In the gas phase it dissociatesto give nitrogen dioxideN<sub>2</sub>O<sub>4</sub>?2NO<sub>2</sub>Because of the unpaired electron thisis paramagnetic and brown. LiquidN<sub>2</sub>O<sub>4</sub> has been widely studied as anonaqueous solvent system (selfionizesto NO<sup>+</sup> and NO<sub>3</sub><sup>-</sup>). Dinitrogentetroxide, along with other nitrogenoxides, is a product of combustionengines and is thought to be involvedin the depletion of stratosphericozone.

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