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Iodine trichloride

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USE
Iodine trichloride decomposes on heating at 77&deg;C, forming iodine monochloride and chlorine:<br /> ICl3 &rarr;ICl + Cl2<br /> It dissolves in concentrated hydrochloric acid , forming HICl4&bull;4H2O:<br /> ICl3 + HCl + 4H2O &rarr; HICl4&bull;4H2O<br /> Iodine trichloride hydrolyzes in water or dilute acids, the products depending upon reaction conditions. This reaction usually is similar to iodine monochloride:<br /> 4ICl3 + 6H2O &rarr; I2 + 6HCl + 2HIO3 + 3Cl2<br /> It combines with potassium chloride, forming a complex salt, KICl4:<br /> ICl3 + KCl &rarr; KICl4<br /> Reaction with acetylene produces chlorovinyl iododichloride, containing two active chlorine atoms attached to the iodine atom:<br /> ICl3 + HC&equiv;CH &rarr; ClCH=CHICl2<br /> The above product has many applications in chemical synthesis.
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