PricePropertiesSafety InformationDescription
ChemicalBook > CAS DataBase List > METHYL ISOCYANOACETATE

METHYL ISOCYANOACETATE

  • $31 - $140
  • Product name:METHYL ISOCYANOACETATE
  • CAS:39687-95-1
  • MF: C4H5NO2
  • MW:99.09
  • EINECS:254-593-8
  • MDL Number:MFCD00000006
  • Synonyms:Methyl isocyanoacetate, technical grade;Methyl isocyanoacetate, 95%, tech.;(2-Oxo-2-methoxyethyl) isocyanide;2-Isocyanoacetic acid methyl ester;2-Oxo-2-methoxyethyl isocyanide;Methyl 2-isocyanoacetate;Methyl isocyanoacetate, tech., 95% 5GR;Acetic acid, 2-isocyano-, Methyl ester
Price
  • Brand:Alfa Aesar
  • Product number:H31069
  • Product nameMethyl isocyanoacetate, 95%
  • Purity:
  • Packaging:1g
  • Price:$31
  • Updated:2021/3/22 17:32:12
  • Buy:Buy
  • Brand:Sigma-Aldrich
  • Product number:238880
  • Product nameMethyl isocyanoacetate
  • Purity:technical grade, 95%
  • Packaging:1g
  • Price:$51.9
  • Updated:2021/3/22 19:32:46
  • Buy:Buy
  • Brand:Sigma-Aldrich
  • Product number:238880
  • Product nameMethyl isocyanoacetate
  • Purity:technical grade, 95%
  • Packaging:5g
  • Price:$128
  • Updated:2021/3/22 19:32:45
  • Buy:Buy
  • Brand:TCI Chemical
  • Product number:M2549
  • Product nameMethyl Isocyanoacetate
  • Purity:>97.0%(GC)
  • Packaging:1g
  • Price:$41
  • Updated:2021/3/22 18:33:11
  • Buy:Buy
  • Brand:TCI Chemical
  • Product number:M2549
  • Product nameMethyl Isocyanoacetate
  • Purity:>97.0%(GC)
  • Packaging:5g
  • Price:$140
  • Updated:2021/3/22 18:33:10
  • Buy:Buy
Properties
  • Boiling point:75-76 °C10 mm Hg(lit.)
  • Density 1.09 g/mL at 25 °C(lit.)
  • refractive index n20/D 1.417(lit.)
  • Flash point:193 °F
  • storage temp. −20°C
  • form Liquid
  • color Clear yellow to brown
  • Water Solubility Miscible with organic solvents. Slightly miscible with water.
  • BRN 3537963
  • CAS DataBase Reference39687-95-1(CAS DataBase Reference)
Safety Information
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements
  • H227:Combustible liquid
  • H302:Harmful if swallowed
  • H312:Harmful in contact with skin
  • H314:Causes severe skin burns and eye damage
  • H318:Causes serious eye damage
  • H331:Toxic if inhaled
  • Precautionary statements
  • P280:Wear protective gloves/protective clothing/eye protection/face protection.
  • P310:Immediately call a POISON CENTER or doctor/physician.
  • P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
  • P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
  • P405:Store locked up.

Description

Methyl isocyanoacetate is used in the copper-catalyzed, diastereoselective synthesis of oxazolines. It is involved in the direct aldol reaction with carbonyl compounds to prepare corresponding oxazoline by using catechol-copper network catalyst. Further, it is also involved in four-component Ugi condensation reaction. It undergoes asymmetric aldol reaction with fluorinated benzaldehyde using gold(I) as a catalyst.


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