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ChemicalBook >> CAS DataBase List >>Anisole

Anisole suppliers

Anisole

CAS:: 100-66-3

MF:: C7H8O

MW:: 108.14

SecurityInformation

Symbol(GHS) ：: GHS02,GHS07

Signal word ：: Warning

Hazard statements ：: H226-H336

Precautionary statements ：: P210-P233-P240-P241-P242-P243

Hazard Codes ：: Xn,Xi

Risk Statements ：: 10-38-20-36/37

Safety Statements ：: 37/39-26-16-24/25

RIDADR ：: UN 2222 3/PG 3

WGK Germany ：: 2

RTECS ：: BZ8050000

Autoignition Temperature：: 887 °F

TSCA ：: Yes

HazardClass ：: 3

PackingGroup ：: III

HS Code ：: 29093090

Toxicity：: LD50 orally in rats: 3700 mg/kg (Taylor)

Use：: Anisole, also known as anise ether, methoxybenzene methyl phenyl ether, is a colorless liquid with an odor of anise, sweet, naturally present in the tarragon oil, insoluble in water, soluble in alcohol, ether, acetone, soluble in benzene. It irritates the eyes and mucous membranes. It is obtained originally from distilled methyl salicylate or methoxybenzoate, is now mainly produced through the reaction of methylating agent of dimethyl sulfate with phenol in alkaline aqueous solution. Anisole is prone to start Electrophilic substitution reaction in aromatic nucleus, and condensed with formaldehyde to produce viscous oil or resin material, reacts with phosphorus trichloride to produce chlorine anisole and a small amount of o-chloro product, reacts with thionyl chloride to produce 2,4,6-trichloroanisole. In addition, anisole is heated to react with hydrobromic or hydroiodic, carbon-oxygen bond cleaves, phenol and halogenated methane is produced, which is an important method for determining methoxy group of benzene ring. The above information is edited by the chemicalbook of Yan Yanyong.

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