2-요오도-4-아세틸페놀

그림문자(GHS)

• 그림문자(GHS)

  

• 신호 어

  Danger

• 유해·위험 문구

  H302：삼키면 유해함

  H318：눈에 심한 손상을 일으킴

• 예방조치문구

  P280：보호장갑/보호의/보안경/안면보호구를 착용하시오.

2-요오도-4-아세틸페놀 화학적 특성, 용도, 생산

• 용도

  Reactant for:
  
  • Preparation of cyclopentene fused benzofurans and indoles via Pd-catalyzed tandem ring opening-ring closing reaction with diazabicyclic alkenes
  • Highly regioselective synthesis of spirocyclic compounds by a palladium-catalyzed intermolecular tandem reaction
  • Regioselective synthesis of indene derivatives via Pd/C-catalyzed cyclization reaction in air
  • Preparation of carbazoles via cross-coupling with silylaryl triflates followed by palladium-catalyzed cyclization
  • Stereoselective preparation of heteropolycyclic compounds via palladium-catalyzed stereoselective heteroannulation of with cyclic alkenes
  • Preparation of disubstituted coumarins via palladium-catalyzed carbonylative annulation of internal alkynes
  • Preparation of arylalkynes, benzofurans and indoles via Sonogashira coupling and cyclization on alumina

• 제조 방법

  Preparation by reaction of iodine and potassium iodide on 4-hydroxyacetophenone in aqueous ammonium hydroxide at r.t. (54–57%).

• Synthesis Reference(s)

  Journal of Medicinal Chemistry, 23, p. 738, 1980 DOI: 10.1021/jm00181a008

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