클로로(2,2′:6′,2"-TERPYRIDINE)백금(II)염화물이수화물

클로로(2,2′:6′,2"-TERPYRIDINE)백금(II)염화물이수화물 화학적 특성, 용도, 생산

• Purification Methods

  Recrystallise it from hot dilute HCl, and on cooling it gives the red dihydrate. The trihydrate crystallises slowly from a cold aqueous solution and is dried in air. The red dihydrate can be obtained from the trihydrate by desiccation over conc H2SO4, by washing with EtOH or by precipitating from a warm aqueous solution with HCl. The dihydrate is also formed by decomposing the black trihydrate form by heating in water (slowly), or more rapidly with hot 2N HCl. [Morgan & Burstall J Chem Soc 1498 1934, Lippard Acc Chem Res 11 211 1987.]

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