티오날리드

그림문자(GHS)

• 그림문자(GHS)

  

• 신호 어

  Danger

• 유해·위험 문구

  H315：피부에 자극을 일으킴

  H318：눈에 심한 손상을 일으킴

  H335：호흡 자극성을 일으킬 수 있음

  H411：장기적 영향에 의해 수생생물에 유독함

• 예방조치문구

  P264：취급 후에는 손을 철저히 씻으시오.

  P264：취급 후에는 손을 철저히 씻으시오.

  P280：보호장갑/보호의/보안경/안면보호구를 착용하시오.

  P302+P352：피부에 묻으면 다량의 물로 씻으시오.

  P305+P351+P338：눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

  P310：즉시 의료기관(의사)의 진찰을 받으시오. 삼켰다면 즉시 의료기관(의사)의 도움을 받으시오.

  P321：(…) 처치를 하시오.

  P332+P313：피부 자극이 생기면 의학적인 조치· 조언을 구하시오.

  P362：오염된 의복을 벗고 세척 후에 재사용하기

티오날리드 화학적 특성, 용도, 생산

• 용도

  Thionalide reacts with a variety of metal ions to give chelate complexes which are sparingly soluble in water. The difference in stability of complexes formed by the reagent with various metal ions in some cases assures a certain analytical selectivity.
  1. Copper(II), silver(I), mercury(II), bismuth(III), arsenic(III), tin(IV), gold(I), platinum(IV) and palladium(II) give precipitates with the reagent in acidic media (mineral acids).
  2. The copper(II), mercury(II), cadmium(II), thallium(I) and gold(I) complexes precipitate from alkaline solutions containing tartrate.
  3. Thallium(I), antimony(III) and bismuth(III) complexes are precipitated by the reagent from solutions containing cyanide and tartrate.
  4. The thallium(I) complex also precipitates from alkaline (sodium hydroxide) solution containing cyanide and tartrate.
  The above classification shows that the reaction can be made specific for thallium by appropriate choice of the pH of the solution and application of suitable masking agents. Similarly, the selectivity of the precipitation reaction can be increased for other ions too, by application of other masking agents. For instance, tin(IV) can be masked selectively in the presence of arsenic(III) and antimony(III) with phosphoric acid, while these latter two ions can be precipitated with thionalide.
  The analytical application of thionalide is stimulated by the fact that its metal complexes are of stoichiometric composition, and can be dried at 105-110°C and weighed directly.
  The reagent may also be utilized in volumetric analytical procedures. The thionalide content, which is equivalent to the metal to be determined, can be titrated directly iodometrically, according to the equation: 2C10H7-NH-CO-CH2-SH+I2=C10H7-NH-CO-CH2-S-S-CH2-CO-NH-C10H7+2HI.

티오날리드 공급 업체

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