Chemically Strontium bromate is soluble in water (30.9 g/100 ml
at 20°C), and is a moderately strong oxidizing agent. It
is also toxic if ingested and irritates the skin and respiratory
tract if come into contact with or inhaled,
respectively. Strontium bromate is rarely used in the laboratory or
in Industry. It is available commercially but in limited
quantities.
化学的特性
Colorless or yellowish crystals, lustrous
powder, hygroscopic. Soluble in water. Loses water at 120C, decomposes at 240C.
製造方法
Strontium Bromate can be prepared by
reacting strontium hydroxide with sodium bromate or
by reacting strontium sulfate with barium bromate:
Sr(OH)2＋ 2NaBrO3→Sr(BrO3)2＋ 2NaOH
SrSO4 (aq)＋ Ba(BrO3)2 (solid)→Sr(BrO3)2 (aq)＋ BaSO4 (solid)
Of the two methods, the latter seems to be more stable
since the temperature can be as high as 80°C in solution.
The usual product is a monohydrate, Sr(BrO3)2·H2O.
Sr(BrO3)·H2O occurs as small, colorless but lustrous,
monoclinic crystals which are prismatic in nature. It is
somewhat soluble in water and loses its water of hydration
if heated to about 110°C. It decomposes at 240°C forming strontium bromide and oxygen.
危険性
Strong oxidant, fire risk in contact with
organic materials.
