ベンゾ[e]ピレン

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H350：発がんのおそれ

  H410：長期的影響により水生生物に非常に強い毒性

• 注意書き

  P201：使用前に取扱説明書を入手すること。

  P273：環境への放出を避けること。

  P308+P313：暴露または暴露の懸念がある場合：医師の診断/手当てを 受けること。

ベンゾ[e]ピレン 価格

ベンゾ[e]ピレン 化学特性,用途語,生産方法

• 化学的特性

  yellow to yellow-green crystalline powder

• 物理的性質

  Crystalline, solid, prisms, or plates. Benzo[e]pyrene is sensitive to ultraviolet light and may degrade into diones.

• 使用

  Used for studies of immune suppressive activity of bezo[e]Pyrene on antibody response to DNP-Ficoll and sheep erythrocytes and "dispersive liquid -liquid micro extraction” technique by extracting organic compounds from water samples.

• 定義

  ChEBI: An ortho- and peri-fused polycyclic arene consisting of five fused benzene rings. It is listed as a Group 3 carcinogen by the IARC.

• 一般的な説明

  Colorless crystals or white crystalline solid.

• 空気と水の反応

  Insoluble in water.

• 反応プロフィール

  BENZO[E]PYRENE may be sensitive to prolonged exposure to light.

• 健康ハザード

  There is very little information available onits toxicity. The oral toxicity is expected to below. Its carcinogenic potential is lower thanthat of benz[a]pyrene. Animal studies gaveinconclusive results. Oral administration mayproduce tumors in the stomach. However, theevidence of carcinogenicity of this compoundin animals is inadequate. Benz[e]pyrene isa mutagen, testing positive to the histidinereversion–Ames test and in vitro unscheduled DNA synthesis (UDS)–human fibroblast.

• 火災危険

  Flash point data for BENZO[E]PYRENE are not available. BENZO[E]PYRENE is probably combustible.

• 安全性プロファイル

  For occupational chemicalanalysis use NIOSH: Polynuclear Aromatic Hydrocarbons(HPLC), 5506; (GC), 5515.

• 環境運命予測

  Photolytic. Schwarz and Wasik (1976) reported a fluorescence quantum yield of ≈ 0.3 for benzo[e]pyrene in water.
  Chemical/Physical. Benzo[e]pyrene will not hydrolyze because it has no hydrolyzable functional group.

• 純化方法

  Purify it by passage through an Al2O3 column (Woelm, basic, activity I) and elute with *C6H6 and recrystallise from 2 volumes of EtOH/*C6H6 (4:1). It forms colourless or light yellow prisms or needles. [Campbell J Chem Soc 3659 1954, Buchta & Kr.ger Justus Liebigs Ann Chem 705 190 1967.] The 1,3,5-trinitrobenzene complex has m 253-254o (orange needles from EtOH), the picrate prepared by mixing 20mg in 1mL of *C6H6 with 20mg of picric acid in 2mL *C6H6, collecting the deep red crystals, and recrystallising from *C6H6 has m 228-229o [NMR: Cobb & Memory J Chem Phys 47 2020 1967]. [Beilstein 5 III 2520, 5 I V 2689.] CARCINOGEN.

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ベンゾ[e]ピレン スペクトルデータ(¹HNMR、¹³CNMR、IR1、IR2、MS)

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