3,6-ジクロロ-2-メトキシ安息香酸塩化物

化学名:3,6-ジクロロ-2-メトキシ安息香酸塩化物

CAS番号.1918-00-9

英語名:Dicamba

CBNumberCB5458633

MFC8H6Cl2O3

MW221.04

MOL File1918-00-9.mol

别名

3,6-ジクロロ-2-メトキシ安息香酸塩化物

ダイカンバ標準品

ジカンバ

3,6-ジクロロ-2-メトキシ安息香酸塩化物物理性質

融点	112-116 °C (lit.)
沸点	316.96°C (rough estimate)
比重(密度)	1.57
屈折率	1.5000 (estimate)
闪点	2 °C
貯蔵温度	2-8°C
溶解性	クロロホルム（微量）、メタノール（微量）
酸解離定数(Pka)	2.40±0.25(Predicted)
外見	クリスタル
色	白い
水溶解度	50g/100mL
極大吸収波長 (λmax)	223nm(lit.)
Merck	14,3040
BRN	2453039
Henry's Law Constant	4.5×10³ mol/(m³Pa) at 25℃, Duchowicz et al. (2020)
暴露限界値	TLV-TWA: 0.1 mg/m3, Inhalable fraction and vapor
主な用途	農業環境
InChI	1S/C8H6Cl2O3/c1-13-7-5(10)3-2-4(9)6(7)8(11)12/h2-3H,1H3,(H,11,12)
InChIKey	IWEDIXLBFLAXBO-UHFFFAOYSA-N
SMILES	COc1c(Cl)ccc(Cl)c1C(O)=O
LogP	2.210
CAS データベース	1918-00-9(CAS DataBase Reference)
NISTの化学物質情報	Benzoic acid, 3,6-dichloro-2-methoxy-(1918-00-9)
EPAの化学物質情報	Dicamba (1918-00-9)

安全性情報

主な危険性	Xn,N,F
Rフレーズ	22-41-52/53-36-20/21/22-11
Sフレーズ	26-61-36-16
RIDADR	UN 3077 9/PG 3
WGK Germany	2
RTECS 番号	DG7525000
HSコード	29189900
ストレージクラス	11 - Combustible Solids
Hazard Classifications	Acute Tox. 4 Oral Aquatic Chronic 3 Eye Dam. 1
有毒物質データの	1918-00-9(Hazardous Substances Data)
毒性	LD50 orally in rats: 1040 mg/kg (Bailey, White)
化審法	(3)-3053

危険有害性情報のコード(GHS)

3,6-ジクロロ-2-メトキシ安息香酸塩化物価格

製品番号	包装	価格	製品説明	購入
富士フイルム和光純薬株式会社(wako) W01ACSP-008NB-250	250mg	￥20000	ジカンバ	購入
富士フイルム和光純薬株式会社(wako) W01ACSP-008N	10mg	￥5300	ジカンバ	購入
東京化成工業 D4800	200mg	￥10000	ジカンバ >98.0%(GC)(T)	購入
関東化学株式会社(KANTO) 49865-28	250mg	￥22000	ジカンバ標準品（ダイカンバ標準品）	購入
関東化学株式会社(KANTO) 10109-96	200mg	￥11500	ダイカンバ標準品（ジカンバ標準品） >98.0%(HLC)	購入

3,6-ジクロロ-2-メトキシ安息香酸塩化物化学特性,用途語,生産方法

外観
白色, 結晶性粉末～粉末
溶解性
エタノール, アセトンに易溶。キシレンに可溶。水に難溶。
農薬用途
除草剤
説明
Dicamba was introduced in the 1960s and is selective in cereals, corn (Zea mays), sugar cane (Saccharum spp.), asparagus (Asparagus officinalis), and turf for the pre- and post-emergence control of annual and perennial broadleaf weeds. Dicamba exhibits lowto- moderate persistence in most soils. See Table 10 for the nomenclature, chemical structure, and physical and chemical properties of dicamba.
使用
Dicamba is mainly used as an herbicide to control weeds, dock, bracken, and brush. Dicamba is frequently applied with other herbicides, including atrazine, glyphosate, imazethapyr, ioxynil, and mecoprop.
定義
ChEBI: A methoxybenzoic acid that is O-methylsalicylic acid substituted by chloro groups at positions 3 and 6.
一般的な説明
Dicamba is a white solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Since Dicamba is a liquid Dicamba can easily penetrate the soil and contaminate groundwater and nearby streams. Dicamba can cause illness by inhalation, skin absorption and/or ingestion. Dicamba is used as a herbicide.
健康ハザード
SOLID: Harmful if swallowed.
火災危険
Not flammable.
农业用途
Herbicide: Used to control annual and perennial broadleaf weeds in corn, sorghum, small grains, pastures, hay, rangeland, sugarcane, asparagus, turf, grass-seed crops, and non-croplands. It can be applied to the leaves or to the soil. Dicamba controls annual and perennial broadleaf weeds in grain crops and grasslands, and it is used to control brush and bracken in pastures. It will kill broadleaf weeds before and after they sprout. Legumes will be killed by dicamba. In combination with a phenoxyalkanoic acid or other herbicide, dicamba is used in pastures, range land, and non-crop areas such as fence-rows and roadways to control weeds.
製品名
BANEX®; BANLEN®; BANVEL®; BANVEL 4S®; BANVEL 4WS®; BANVEL CST®; BANVEL HERBICIDE®; BANVEL II HERBICIDE®; BRUSH BUSTER®; BUSHWHACKER®; CADENCE®; CASWELL No. 295®; CLARITY®; COMPOUND B DICAMBA®; DIANATE®; DISTINCT®; DYVEL®; FALLOWMASTER®; FLOWMASTER®; GORDON’S TRIGUARD®; GORDON’S TRI-MEC®; MARKSMAN®; MEDIBEN®; NORTHSTAR®; SUMMIT®; TARGET®; TRACKER®; TROOPER®; VANQUISH®; VELSICOL 58-CS-11®; VELSICOL COMPOUND R®; WEEDMASTER®; YUKON®
薬理学
Dicamba is highly mobile in soils and will leach or move upward depending on the flux of the soil water. Adsorption to soils is generally limited, although a few studies using acidic kaolinite and muck soils showed that dicamba was adsorbed to these soils. Adsorption of dicamba is greatest at low soil pHs and is minimal at pHs greater than 6.0. Because dicamba is highly water soluble, it is reasonable to expect that some loss may occur via soil water runoff from the application zone. However, studies conducted by Trichelle et al. (44) showed that such losses were minimal, i.e., less than 5.5% of applied. The rate of dicamba volatilization is not clear, although it is likely that it does occur to some extent. On planchets, approximately 50% of applied dicamba volatilized over a period of 11 weeks. The significance of this result is questionable, because in a similar study using soil, there was no appreciable volatilization (45).
安全性プロファイル
Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl-.
Mode of action
DICAMBA HD 5 is readily absorbed by plants through shoot and root uptake, translocates throughout the plant's system, and accumulates in areas of active growth. This product interferes with the plant's growth hormones (auxins) resulting in death of many broadleaf weeds.

3,6-ジクロロ-2-メトキシ安息香酸塩化物上流と下流の製品情報

3,6-ジクロロ-2-メトキシ安息香酸塩化物生産企業

3,6-ジクロロ-2-メトキシ安息香酸塩化物スペクトルデータ(¹HNMR、¹³CNMR、IR1、IR2、MS)

1918-00-9, 3,6-ジクロロ-2-メトキシ安息香酸塩化物キーワード

Send Inquriy

3,6-ジクロロ-2-メトキシ安息香酸 塩化物

危険有害性情報のコード(GHS)

3,6-ジクロロ-2-メトキシ安息香酸 塩化物 価格

3,6-ジクロロ-2-メトキシ安息香酸 塩化物 化学特性,用途語,生産方法

3,6-ジクロロ-2-メトキシ安息香酸 塩化物 上流と下流の製品情報

3,6-ジクロロ-2-メトキシ安息香酸 塩化物 生産企業

3,6-ジクロロ-2-メトキシ安息香酸 塩化物 スペクトルデータ(1HNMR、13CNMR、IR1、IR2、MS)

1918-00-9, 3,6-ジクロロ-2-メトキシ安息香酸 塩化物 キーワード

3,6-ジクロロ-2-メトキシ安息香酸塩化物

3,6-ジクロロ-2-メトキシ安息香酸塩化物価格

3,6-ジクロロ-2-メトキシ安息香酸塩化物化学特性,用途語,生産方法

3,6-ジクロロ-2-メトキシ安息香酸塩化物上流と下流の製品情報

3,6-ジクロロ-2-メトキシ安息香酸塩化物生産企業

3,6-ジクロロ-2-メトキシ安息香酸塩化物スペクトルデータ(¹HNMR、¹³CNMR、IR1、IR2、MS)

1918-00-9, 3,6-ジクロロ-2-メトキシ安息香酸塩化物キーワード