ペルクロリルフルオリド

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H270：発火または火災助長のおそれ；酸化性物質

  H314：重篤な皮膚の薬傷?眼の損傷

  H330：吸入すると生命に危険

• 注意書き

  P220：衣類/．．．/可燃物から遠ざけること。

  P244：減圧バルブにはグリースおよび油を使用しないこと。

  P260：粉じん/煙/ガス/ミスト/蒸気/スプレーを吸入しないこ と。

  P264：取扱い後は皮膚をよく洗うこと。

  P264：取扱い後は手や顔をよく洗うこと。

  P271：屋外または換気の良い場所でのみ使用すること。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P284：呼吸用保護具を着用すること。

  P301+P330+P331：飲み込んだ場合：口をすすぐこと。無理に吐かせ ないこと。

  P303+P361+P353：皮膚（または髪）に付着した場合：直ちに汚染された衣 類をすべて脱ぐこと/取り除くこと。皮膚を流水/シャワー で洗うこと。

  P304+P340：吸入した場合：空気の新鮮な場所に移し、呼吸しやすい 姿勢で休息させること。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

  P310：ただちに医師に連絡すること。

  P320：特別な治療が緊急に必要である（このラベ ルの．．．を見よ）。

  P321：特別な処置が必要である（このラベルの．．． を見よ）。

  P363：汚染された衣類を再使用す場合には洗濯をすること。

  P370+P376：火災の場合：安全に対処できるならば漏洩を止めること。

  P403：換気の良い場所で保管すること。

  P403+P233：換気の良い場所で保管すること。容器を密閉 しておくこと。

  P405：施錠して保管すること。

  P501：内容物/容器を．．．に廃棄すること。

ペルクロリルフルオリド 化学特性,用途語,生産方法

• 化学的特性

  Perchloryl fluoride is a colorless gas. Characteristic sweet odor. Shipped as a liquefied compressed gas.

• 使用

  perchloryl fluoride's uses are as an effective fluorinating agent, as an oxidant in rocket fuels, and as a gaseous dielectric for transformers.

• 一般的な説明

  Perchloryl fluoride is a colorless, non corrosive gas with a characteristic sweet odor. Contact with the material may cause irritation to skin, eyes, and mucous membranes. Perchloryl fluoride is very toxic by inhalation and skin absorption. Under prolonged exposure to fire or intense heat the containers may violently rupture and rocket.

• 空気と水の反応

  Slightly soluble in water.

• 反応プロフィール

  Perchloryl fluoride is a propellant; a powerful oxidant. Perchloryl fluoride ignites upon contact with alcohols, amines, ammonia, beryllium alkyls, boranes, dicyanogen, hydrazines, hydrocarbons, hydrogen, nitroalkanes, powdered metals, silanes, or thiols [Bretherick 1979. p.174].

• 健康ハザード

  TOXIC; may be fatal if inhaled or absorbed through skin. Fire will produce irritating, corrosive and/or toxic gases. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Runoff from fire control may cause pollution.

• 火災危険

  Substance does not burn but will support combustion. Vapors from liquefied gas are initially heavier than air and spread along ground. These are strong oxidizers and will react vigorously or explosively with many materials including fuels. May ignite combustibles (wood, paper, oil, clothing, etc.). Some will react violently with air, moist air and/or water. Cylinders exposed to fire may vent and release toxic and/or corrosive gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket.

• 安全性プロファイル

  A poison gas which forms methemoglobin in the body and destroys red cells causing anemia, anorexia, and cyanosis. Recovery is said to be rapid, leaving no permanent physiological damage. Can be absorbed through the skin. Its odor can be detected as low as 10 ppm although this cannot be relied upon as an indication of toxic concentration in air. While nonflammable, it supports combustion. It is a powerful oxidzer. Moderately explosive. Potentially explosive reactions with combustible gases or vapors. benzene + aluminum trichloride, benzocyclobutene + butyllithium + potassium tert-butoxide, calcium acetylide, potassium cyanide, potassium thiocyanate, sodium iochde, charcoal, ethyl-4-fluorobenzoylacetate, hydrocarbons, hydrogen sulfide, nitrogen oxide, sulfur dichloride, vinylidene chloride, 3a-hydroxy-5p-androstane-1 1,17-di0ne-l 7hydrazone, lithiated compounds, 2lithio (dimet hy laminomethyl)f erroxene, methyl-2-bromo-5,5-ethylene dioxy(2,2,1)bicycloheptane-7-carboxylate, aliphatic heterocyclic amines, sodium methoxide + methanol, vinylidene chloride. Reacts to form explosive products with nitrogenous bases (e.g., isopropylamine, isobutylamine, aniline, phenyl hydrazine, 1,2-diphenyl hydrazine), sawdust, lampblack. Violent reaction with finely dwided organic materials. A fluorinating agent in chemical synthesis, and an oxidant in rocket fuel. When heated to decomposition it emits toxic fumes of Fand Cl-. See also FLUORINE and PERCHLORATES

• 職業ばく露

  Perchloryl fluoride has been used as a liquid oxidant in rocket propellant combinations; as an insulating gas in high voltage electrical systems; as a fluorinating agent in organic synthesis.

• 輸送方法

  UN3083 Perchloryl fluoride, Hazard Class: 2.3; Labels: 2.3-Poisonous gas, 5.1-Oxidizer, Inhalation Hazard Zone B. UN3157 Liquefied gas, oxidizing, n.o.s., Hazard Class: 2.2; Labels: 2.2-Non-flammable compressed gas, 5.1-Oxidizer, Technical Name Required. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.

• 不和合性

  A strong oxidizing gas. Violent reaction with benzene, calcium hydride; combustibles, olefins, strong bases; sulfur, sulfuric acid; amines, reducing agents; alcohols. Contact with carbonaceous materials (such as charcoal) or finely divided metals (such as powdered magnesium and aluminum, zinc) are a fire and explosion hazard. Attacks some plastics, rubber, and coatings

• 廃棄物の処理

  Return refillable compressed gas cylinders to supplier. Incineration together with flammable solvent in furnace equipped with afterburner and scrubber.

ペルクロリルフルオリド 生産企業

Global(6)Suppliers

7616-94-6, ペルクロリルフルオリド キーワード