チオりん酸O,O-ジメチルS-[2-[1-(メチルカルバモイル)エチルチオ]エチル]

化学名:チオりん酸O,O-ジメチルS-[2-[1-(メチルカルバモイル)エチルチオ]エチル]

CAS番号.2275-23-2

英語名:Vamidothion

CBNumberCB2771555

MFC8H18NO4PS2

MW287.34

MOL File2275-23-2.mol

别名

バミドエート

バミドチオン

キルバール

チオりん酸O,O-ジメチルS-[2-[1-(メチルカルバモイル)エチルチオ]エチル]物理性質

融点	35.5°C
沸点	72.8°C
比重(密度)	1.240±0.06 g/cm3(Predicted)
蒸気圧	9×10^-6 Pa (est.)
闪点	2 °C
貯蔵温度	0-6°C
水溶解度	4,000,000 mg l^-1
酸解離定数(Pka)	15.22±0.46(Predicted)
CAS データベース	2275-23-2(CAS DataBase Reference)
NISTの化学物質情報	Phosphorothioic acid, o,o-dimethyl s-[2-[[1-methyl-2-(methylamino)-2-oxoethyl]thio]ethyl] ester(2275-23-2)
EPAの化学物質情報	Vamidothion (2275-23-2)

安全性情報

主な危険性	T;N,N,T,Xn,F
Rフレーズ	21-25-50-36-20/21/22-11
Sフレーズ	36/37-45-61-16
RIDADR	UN 2811
WGK Germany	2
RTECS 番号	TF7900000
国連危険物分類	6.1(b)
容器等級	III
有毒物質データの	2275-23-2(Hazardous Substances Data)
毒性	LD50 oral in rabbit: 160mg/kg
毒劇物取締法	III

危険有害性情報のコード(GHS)

チオりん酸O,O-ジメチルS-[2-[1-(メチルカルバモイル)エチルチオ]エチル] 価格

製品番号	包装	価格	製品説明	購入
富士フイルム和光純薬株式会社(wako) W01W0122-0171	100mg	￥19600	バミドチオン標準品 98.0+% (qNMR)<BR>98.0+% (Capillary GC)	購入
富士フイルム和光純薬株式会社(wako) W01ACSP-350N	10mg	￥27600	バミドチオン	購入
関東化学株式会社(KANTO) 49802-56	100mg	￥50000	バミドチオン標準品	購入
Sigma-Aldrich Japan 32931	2ml	￥9820	バミドチオン溶液 100?μg/mL in acetonitrile, PESTANAL?, analytical standard	購入
林純薬工業株式会社 99052146	100mg	￥18000	バミドチオン ≧90.0%	購入

MSDS Information

チオりん酸O,O-ジメチルS-[2-[1-(メチルカルバモイル)エチルチオ]エチル] 化学特性,用途語,生産方法

外観
白色, 結晶性粉末〜粉末又は塊
溶解性
アセトンに溶ける。
農薬用途
殺虫剤、ダニ駆除剤
使用上の注意
アルゴン封入
説明
Vamidothion is a colorless crystalline substance,. It is readily soluble in water (4 kg/L) and most organic solvents except aliphatic hydrocarbons. Log Kow = 0.12. It decomposes in strong alkaline and acidic media.
使用
Vamidothion is a phosphorothioic insecticide for apples and potatoes.
定義
ChEBI: An organic thiophosphate that is N-methyl-2-[(2-sulfanylethyl)sulfanyl]propanamide in which the thiol group has been converted to the corresponding O,O-dimethyl thiophoshate. Formerly used as an inse ticide and acaricide, it is no longer approved for use within the European Union.
薬理学
Pyriproxyfen formulations demonstrate persistent efficacy. For example, a water-based 5.3% pyriproxyfen spot-on formulation applied to cats was reported to completely prevent the hatching of flea eggs for at least 46 days after treatment and continued to provide greater than 96% control until day 60 (57). Because pyriproxyfen is efficacious at very low concentrations, trace amounts of the chemical, when transferred from treated pets to their environments, are sufficient to inhibit the development of larvae.
代謝経路
Vamidothion is mainly metabolised via oxidation to its sulfoxide; further oxidation to the corresponding sulfone has been observed in houseflies but occurs much less readily than with other thioether-containing organophosphates (e.g. phorate). The sulfoxide is then hydrolysed via P-S and C-S bond cleavage to give the thiol or hydroxyl derivatives and dimethyl phosphate and O,O-dimethyl phosphorothioate respectively. O-Demethylation apparently occurs as a major degradation process in plants but has not been observed in soil or in animals. N-Demethylation and hydrolysis to the corresponding carboxylic acid, such as occurs with dimethoate, does not apparently happen in the case of vamidothion.

チオりん酸O,O-ジメチルS-[2-[1-(メチルカルバモイル)エチルチオ]エチル] 生産企業

2275-23-2, チオりん酸O,O-ジメチルS-[2-[1-(メチルカルバモイル)エチルチオ]エチル] キーワード

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