2,2'-オキシビス(1-クロロプロパン)

化学名:2,2'-オキシビス(1-クロロプロパン)

CAS番号.108-60-1

英語名:BIS(2-CHLOROISOPROPYL)ETHER

CBNumberCB2184898

MFC6H12Cl2O

MW171.06

MOL File108-60-1.mol

别名

2,2'-オキシビス(1-クロロプロパン)

DCIP【ネマトシド】

ネマモルト

2,2'-オキシビス(1-クロロプロパン)物理性質

融点	-97℃
沸点	242.21°C (rough estimate)
比重(密度)	1.1030
蒸気圧	0.56 (quoted, Kawamoto and Urano, 1989)
屈折率	1.4505 (estimate)
闪点	11 °C
貯蔵温度	0-6°C
溶解性	アセトン、エタノール、ベンゼン、エーテル (Weast, 1986) およびメタノール、プロパノール、2-ブタノンを含む他の多くの溶媒に可溶。
Henry's Law Constant	0.24 at 25 °C (static headspace-GC, Kawamoto and Urano, 1989)
暴露限界値	No exposure limit is set for this compound. Carcinogen — Animal Limited Evidence (IARC).
CAS データベース	108-60-1
IARC	3 (Vol. 41, Sup 7, 71) 1999
EPAの化学物質情報	Bis(2-chloro-1-methylethyl) ether (108-60-1)

安全性情報

主な危険性	Xn,T,F
Rフレーズ	22-36/37/38-39/23/24/25-23/24/25-11
Sフレーズ	26-45-36/37-16-7
RIDADR	2490
WGK Germany	3
RTECS 番号	KN1750000
国連危険物分類	6.1(a)
容器等級	II
有毒物質データの	108-60-1(Hazardous Substances Data)
毒性	LC50 (48-hour) for carp >40 mg/L (Hartley and Kidd, 1987); acute oral LD50 for rats 503.6 mg/kg (Hartley and Kidd, 1987), 240 mg/kg (RTECS, 1985).
消防法	危険物第4類第三石油類(非水溶性)
化審法	2-380
安衛法	有機溶剤中毒予防規則:第2種有機溶剤,57,57-2
毒劇物取締法	II

危険有害性情報のコード(GHS)

2,2'-オキシビス(1-クロロプロパン) 価格

製品番号	包装	価格	製品説明	購入
富士フイルム和光純薬株式会社(wako) W01ACSAS-E0040	1mL	￥14200	bis(2-Chloroisopropyl)ether (5.0 mg/mL in MeOH)	購入
富士フイルム和光純薬株式会社(wako) W01ACSAPP-9-028	1mL	￥8900	bis(2-Chloro-1-methylethyl)ether (100 μg/mL in Dichloromethane)	購入
関東化学株式会社(KANTO) 49860-30	100mg	￥33000	ビス（２‐クロロ‐１‐メチルエチル）エーテル標準品	購入
関東化学株式会社(KANTO) 49832-02	1mL	￥19000	ビス（２‐クロロ‐１‐メチルエチル）エーテル標準液	購入
Sigma-Aldrich Japan 48498	100mg	￥59800	ビス-(2-クロロイソプロピル)エーテル analytical standard	購入

2,2'-オキシビス(1-クロロプロパン) 化学特性,用途語,生産方法

外観
無色～ほとんど無色, 澄明の液体
溶解性
水に可溶 (12g/100ml, 20℃)。有機溶剤に易溶。水に1.7g/l溶ける。水に極めて溶けにくい。
用途
殺虫剤
説明
Bis-(2-chloroisopropyl) ether is a byproduct in the synthesis of ethylene and propylene glycol that has been found in municipal drinking water in the United States and waterways in the Netherlands where it is considered a persistent organic pollutant (POP). It is mutagenic in the S. typhimurium strains TA 1535 and TA 100 but lacks mutagenic activity in mice.
化学的特性
Clear Colourless Oil
物理的性質
Colorless to light brown oily liquid. Verschueren (1983) reported an odor threshold concentration of 320 ppb.
使用
Bis(2-chloroisopropyl)ether is used as a sol vent for resins, waxes, and oils, and inorganic synthesis.
一般的な説明
Colorless to light brown liquid. Odor threshold concentration 200 μg/L.
空気と水の反応
Subject to peroxidation in air. Insoluble in water.
反応プロフィール
BIS(2-CHLOROISOPROPYL)ETHER oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979 p.151-154, 164].
健康ハザード
Bis(2-chloroisopropyl)ether exhibited moderately toxic and carcinogenic actions intest animals. The acute inhalation toxicity of this compound is considerably lowerthan those of bis(chloromethyl)ether and bis(chloroethyl)ether. Exposure to its vapors cancause irritation of the eyes and upper respiratory tract. Inhalation of 700 ppm of this com pound in air for 5 hours proved fatal to rats
The oral toxicity of bis(2-chloroisopropyl)ether in rats was found to be moderate, withan LD50 value of 240 mg/kg.
The compound is carcinogenic to animals.Although there is no evidence of its carcino genicity in humans, exposure may cause lungcancer.
火災危険
BIS(2-CHLOROISOPROPYL)ETHER is combustible.
職業ばく露
BCIE was previously used as a solvent and as an extractant. It may be formed as a by-product of propylene oxide production. It has been found in industrial waste water and in natural water.
環境運命予測
Biological. When bis(2-chloroisopropyl)ether (5 and 10 mg/L) was statically incubated in the dark at 25°C with yeast extract and settled domestic wastewater inoculum, complete biodegradation was achieved after 14 days (Tabak et al., 1981).
Chemical/Physical. Kollig (1993) reported that bis(2-chloroisopropyl)ether is subject to hydrolysis forming hydrochloric acid and the intermediate (2-hydroxy-isopropyl-2- chloroisopropyl)ether. The latter undergoes further hydrolysis yielding bis
輸送方法
UN2490 Dichloroisopropyl ether, Hazard Class: 6.1; Labels: 6.1—Poisonous materials.
不和合性
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. It may form dangerous peroxides upon standing; may explode when heated.
廃棄物の処理
Use special incinerator due to high HCl content, such as seagoing incinerator ships.

2,2'-オキシビス(1-クロロプロパン) 上流と下流の製品情報

2,2'-オキシビス(1-クロロプロパン) 生産企業

2,2'-オキシビス(1-クロロプロパン) スペクトルデータ(IR1、MS)

108-60-1, 2,2'-オキシビス(1-クロロプロパン) キーワード

Send Inquriy