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Chloro(1,5-cyclooctadiene)rhodium(I) dimer Structure

Chloro(1,5-cyclooctadiene)rhodium(I) dimer

  • Product NameChloro(1,5-cyclooctadiene)rhodium(I) dimer
  • CAS12092-47-6
  • CBNumberCB9406940
  • MFC16H24Cl2Rh2
  • MW493.08
  • EINECS235-157-6
  • MDL NumberMFCD00012415
  • MOL File12092-47-6.mol

Chemical Properties

Melting point: 243 °C (dec.) (lit.)
Density  1.94[at 20℃]
vapor pressure  0Pa at 25℃
storage temp.  Inert atmosphere,Room Temperature
solubility  Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.
form  Crystals or Crystalline Powder
color  Orange to orange-brown
Water Solubility  1.56g/L at 20℃
Sensitive  Air Sensitive & Hygroscopic
Exposure limits ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
Stability: hygroscopic
InChI InChI=1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
InChIKey QSUDXYGZLAJAQU-MIXQCLKLSA-L
SMILES Cl[Rh].C1CCC=CCCC=1.C1CCC=CCCC=1.[Rh]Cl |c:4,8,12,16|
LogP 3.16 at 20℃
NIST Chemistry Reference Bis(1,5-cyclooctadienerhodium chloride)(12092-47-6)
EPA Substance Registry System Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di- (12092-47-6)

Safety

Symbol(GHS) 
Signal word  Warning
Hazard statements  H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
3
TSCA  TSCA listed
HS Code  28439000
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
NFPA 704:
1
0 0

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Chloro(1,5-cyclooctadiene)rhodium(I) dimer Chemical Properties,Usage,Production

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