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cyclopropanol

cyclopropanol Structure
cyclopropanol
  • CAS No.16545-68-9
  • Chemical Name:cyclopropanol
  • CBNumber:CB91318019
  • Molecular Formula:C3H6O
  • Formula Weight:58.08
  • MOL File:16545-68-9.mol
cyclopropanol Property
  • Melting point 180℃
  • Boiling point 101-102℃ (760 Torr)
  • Density 9.9110 g/cm3
  • refractive index 1.4129 (589.3 nm 20℃)
  • storage temp. 2-8°C
  • pka 15.31±0.20(Predicted)
  • InChI InChI=1S/C3H6O/c4-3-1-2-3/h3-4H,1-2H2
  • InChIKey YOXHCYXIAVIFCZ-UHFFFAOYSA-N
  • SMILES C1(O)CC1
  • FDA UNII TK7N9F9R3Y
Safety
  • RIDADR  :UN1993
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H318-H301
  • Precautionary statements P280-P305+P351+P338-P310-P264-P270-P301+P310-P321-P330-P405-P501

cyclopropanol Chemical Properties,Usage,Production

  • Description Cyclopropanols can be readily synthesized via synthetic transformations such as the Kulinkovich cyclopropanation and the Simmons-Smith reaction [1]. Due to the high strains built intrinsically in the three-membered ring, cyclopropanols and their derivatives are highly reactive and can undergo various ring opening/expansion/fragmentation reactions. A significant amount of these ring opening/expansion/fragmentation reactions are catalyzed/promoted by transition metal complexes. In many of these cases, cyclopropanols and their derivatives are considered as the equivalents of homoenolates or β-alkyl radicals.
  • Uses Cyclopropanol is a basic building block.
  • Definition ChEBI: Cyclopropanol is a cyclopropane in which a hydrogen atom is replaced by a hydroxy group. It is a member of cyclopropanes and an aliphatic alcohol.
  • References [1] Xinpei Cai, Mingji Dai, Weida Liang. “Total syntheses via cyclopropanols.” Tetrahedron 75 2 (2019): Pages 193-208.
cyclopropanol Preparation Products And Raw materials
Raw materials
Preparation Products
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cyclopropanol Spectrum
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