ChemicalBook > CAS DataBase List > 4-Methylpyridazine
4-Methylpyridazine
4-Methylpyridazine
- CAS No.1120-88-3
- Chemical Name:4-Methylpyridazine
- CBNumber:CB8468011
- Molecular Formula:C5H6N2
- Formula Weight:94.11
- MOL File:1120-88-3.mol
4-Methylpyridazine Property
- Boiling point 98-100 °C/11 mmHg (lit.)
- Density 1.06 g/mL at 25 °C (lit.)
- refractive index n
20/D 1.521(lit.) - Flash point 222 °F
- storage temp. Sealed in dry,Room Temperature
- pka 3.74±0.10(Predicted)
- form Liquid
- color Clear yellow
- Specific Gravity 1.060
- λmax 292nm(H2O)(lit.)
- BRN 105689
- InChI InChI=1S/C5H6N2/c1-5-2-3-6-7-4-5/h2-4H,1H3
- InChIKey AIKUBOPKWKZULG-UHFFFAOYSA-N
- SMILES C1=NN=CC=C1C
- CAS DataBase Reference 1120-88-3(CAS DataBase Reference)
- UNSPSC Code 12352100
- NACRES NA.22
Safety
- Hazard Codes :Xi
- Risk Statements :36/37/38
- Safety Statements :26-37/39-36
- WGK Germany :3
- HS Code :29339900
-
NFPA 704:
1 2 0
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H315-H319-H335
- Precautionary statements P261-P264-P271-P280-P302+P352-P305+P351+P338
4-Methylpyridazine Price
More Price(2)
- Brand: Sigma-Aldrich(India)
- Product number: 297771
- Product name : 4-Methylpyridazine
- Purity: 97%
- Packaging: 500MG
- Price: ₹8270.3
- Updated: 2022/06/14
- Buy: Buy
- Brand: TCI Chemicals (India)
- Product number: M2343
- Product name : 4-Methylpyridazine
- Purity: min. 98.0 %
- Packaging: 1G
- Price: ₹12500
- Updated: 2022/05/26
- Buy: Buy
4-Methylpyridazine Chemical Properties,Usage,Production
- Chemical Properties Clear yellow liquid
- Uses 4-Methylpyridazine was used in the preparation of series of novel pyridazine derivatives structurally related to bipyridine cardiotonics.
-
Reactions
4-methylpyridazine could be used as a starting material to synthesize a series of novel pyridazine derivatives structurally related to bipyridine cardiotonics[1].
Pyridazine (pydz) and 4-methylpyridazine (4Me-pydz) could form stable bis(monodentate) complexes of general formulae fac-[PtXMe3L2](X = Cl, Br or I) and fac-[ReX(CO)3L2](X = Cl, Br or I). These complexes in above-ambient temperature solutions exhibit 1,2-fluxional shifts between the nitrogen donor pairs of each ring[2]. - General Description Products of reaction of methyl iodide with 4-methylpyridazine has been investigated by NMR spectra. Solvent free oxidation of 4-methylpyridazine by acetyl peroxyborate, peracetic acid and hydrogen peroxide has been reported.
-
References
[1] Haider N, et al. Pyridazine analogues of biologically active compounds. Part 5: Novel potential cardiotonics of the amrinone type. Organic Electronics, 1989.
[2] Abel E, et al. 1,2-Metallotropic shifts in trimethylplatinum(IV) and tricarbonylrhenium(I) halide complexes of pyridazine and 4-methylpyridazine. Journal of the Chemical Society, Dalton Transactions, 1994; 445-455.
4-Methylpyridazine Preparation Products And Raw materials
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