ChemicalBook > CAS DataBase List > 2-METHOXYTETRAHYDROPYRAN
2-METHOXYTETRAHYDROPYRAN
2-METHOXYTETRAHYDROPYRAN
- CAS No.6581-66-4
- Chemical Name:2-METHOXYTETRAHYDROPYRAN
- CBNumber:CB6194233
- Molecular Formula:C6H12O2
- Formula Weight:116.16
- MOL File:6581-66-4.mol
2-METHOXYTETRAHYDROPYRAN Property
- Boiling point 128-129 °C (lit.)
- Density 0.963 g/mL at 25 °C (lit.)
- refractive index n
20/D 1.425(lit.) - Flash point 77 °F
- form liquid
- Specific Gravity 0.963
- UNSPSC Code 12352100
- NACRES NA.22
Safety
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H225
- Precautionary statements P210-P403+P235
2-METHOXYTETRAHYDROPYRAN Price
More Price(2)
- Brand: Sigma-Aldrich(India)
- Product number: 343455
- Product name : 2-Methoxytetrahydropyran
- Purity: 98%
- Packaging: 5G
- Price: ₹4189.28
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 343455
- Product name : 2-Methoxytetrahydropyran
- Purity: 98%
- Packaging: 25G
- Price: ₹16497.3
- Updated: 2022/06/14
- Buy: Buy
2-METHOXYTETRAHYDROPYRAN Chemical Properties,Usage,Production
-
Preparation
To a flask equipped with a stirrer and containing 84.0 gm (1.0 mole) of 2,3-dihydropyran in the presence of 1 ml of cone, hydrochloric acid is added 32.0 gm (1.0 mole) of methanol. The reaction is exothermic and is stirred for 3 hr. Then a few pellets of sodium hydroxide are added to make the reaction basic. The mixture is directly distilled to afford 98.6 gm (85%), b.p. 125°C (760 mm Hg).
- General Description 2-Methoxytetrahydropyran is methoxy-substituted tetrahydropyran. α- and β-glycosidic C1-O1 bonds of the axial and equatorial forms of 2-methoxytetrahydropyran has been investigated by ab initio conformational study. Stereochemical properties of the glycosidic linkage of 2-methoxytetrahydropyran have been studied by the quantum-chemical PCILO method. It undergoes elimination reaction in the gas phase to yield 3, 4-dihydro-2H-pyran and methanol. Proton resonance spectra of 2-methoxytetrahydropyran has been analyzed.
2-METHOXYTETRAHYDROPYRAN Preparation Products And Raw materials
Raw materials
Preparation Products
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