Reaction
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BrettPhosPalladacycle

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BrettPhosPalladacycle Structure
BrettPhosPalladacycle
  • CAS No.1148148-01-9
  • Chemical Name:BrettPhosPalladacycle
  • CBNumber:CB52614378
  • Molecular Formula:C43H63ClNO2PPd
  • Formula Weight:798.83
  • MOL File:1148148-01-9.mol
BrettPhosPalladacycle Property
  • Melting point 198-204 °C
  • form Powder
  • color white
  • UNSPSC Code 12161600
  • NACRES NA.22
Safety
  • Hazard Codes  :Xi
  • Risk Statements  :36/37/38
  • Safety Statements  :26
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H315-H319-H335
  • Precautionary statements P261-P305+P351+P338
BrettPhosPalladacycle Price More Price(5)
  • Brand: Sigma-Aldrich
  • Product number: 718750
  • Product name : BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
  • Purity: may contain up to 1 mole equivalent of MTBE, 97%
  • Packaging: 100MG
  • Price: ₹8469.3
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 718750
  • Product name : BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
  • Purity: may contain up to 1 mole equivalent of MTBE, 97%
  • Packaging: 100MG
  • Price: ₹8469.3
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 718750
  • Product name : BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
  • Purity: may contain up to 1 mole equivalent of MTBE, 97%
  • Packaging: 1G
  • Price: ₹33211.2
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich
  • Product number: 718750
  • Product name : BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
  • Purity: may contain up to 1 mole equivalent of MTBE, 97%
  • Packaging: 5G
  • Price: ₹97469.1
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 718750
  • Product name : BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
  • Purity: may contain up to 1 mole equivalent of MTBE, 97%
  • Packaging: 5G
  • Price: ₹97469.1
  • Updated: 2022/06/14
  • Buy: Buy

BrettPhosPalladacycle Chemical Properties,Usage,Production

  • Reaction
    1. Catalyst for cross-coupling reactions using aryl mesylates with electron-deficient anilines.
    2. Catalyst for rapid C-N bond-forming processes at low catalyst loading.
    3. Cross-coupling of 3-Bromo-2-aminopyridine with primary amines.
    Reactions of 1148148-01-9
  • Uses Application Guide for Palladium Catalyzed Cross-Coupling Reactions

    Catalyst for:
    • C,N-cross coupling of unprotected 3-halo-2-aminopyridines with primary and secondary amines
    • Amination reaction
    • N-arylation of aminophenols
  • General Description BrettPhos Pd G1 is a Buchwald first generation (G1) palladacycle precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The formation of the active Pd(0) species in the G1 precatalyst is easy to generate, requiring merely a deprotonation with a base. The resulting catalyst is very active, even at temperatures down to ?40 °C, and can be used in a variety of cross-coupling protocols.
  • reaction suitability core: palladium
    reaction type: Buchwald-Hartwig Cross Coupling Reaction
    reaction type: Heck Reaction
    reaction type: Hiyama Coupling
    reaction type: Negishi Coupling
    reaction type: Sonogashira Coupling
    reaction type: Stille Coupling
    reaction type: Suzuki-Miyaura Coupling
    reagent type: catalyst
    reaction type: Cross Couplings
BrettPhosPalladacycle Preparation Products And Raw materials
Raw materials
Preparation Products
Global(94)Suppliers
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BrettPhosPalladacycle Spectrum
1148148-01-9, BrettPhosPalladacycleRelated Search:
  • Pd
  • Buchwald Precatalysts Series
  • Buchwald Ligands&Precatalysts
  • 抑制剂
  • 高端化学
  • 钯类贵金属催化剂
  • 有机中间体
  • 金属催化剂
  • 贵金属催化剂
  • 有机膦配体
  • C48H74ClNO3PPd
  • C43H63ClNO2PPd
  • 氯(2-二环己基膦基-3,6-二甲氧基-2,4,6-三异丙基-1,1-联苯)[2-(2-氨基乙基苯基)
  • 氯[2-(二环己基膦基)-3,6-二甲氧基-2'',4'',6''-三异丙基-1,1''-联苯苯基] [2-(2-氨基乙基)苯基]钯(II)
  • 化合物 DICYCLOHEXYL(2',4',6'-TRIISOPROPYL-3,6-DIMETHOXY-[1,1'-BIPHENYL]-2-YL)PHOSPHINE-(2-(2-AMINOETHYL)PHENYL)PALLADIUM(II) CHLORIDE
  • 氯[2-(二环己基膦基)-2',4',6'-三异丙基-3,6-二甲氧基联苯][2-(2-氨乙基)苯基]钯(II)
  • 氯[2-(二环己基膦基)-3,6-二甲氧基-2'',4'',6''-三异丙基-1,1''-联苯苯基][2-(2-氨基乙基)苯基]钯(II)[BRETTPHOSPALLADACYCLEGEN.1
  • BRETTPHOS PD G1有机钯化合物
  • BRETTPHOS PD G1/ (2-二环己基膦-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯)[2-(2-氨基乙基苯基)]氯化钯(II)
  • (2-二环己基膦基-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯)[2-(2-氨基乙基苯基)]氯化钯(II)
  • BRETTPHOS PD G1,甲基叔丁基醚加合物
  • (2-二环己基膦-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯)[2-(2-氨基乙基苯基)]氯化钯(II) BRETTPHOS PALLADACYCLE GEN. 1
  • 二环己基(2',4',6'-三异丙基-3,6-二甲氧基-[1,1'-联苯基] -2-基)膦-(2-(2-氨基乙基)苯基)钯(II)氯化物
  • 氯(2-二环己基膦基-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯)[2-(2-氨基乙基苯基)]钯(II)
  • [2-(二环己基磷)-3,6-甲氧基-2',4',6'-三异丙基-1,1'-联苯][2-(2-氨基乙基)苯]氯化钯
  • (2-二环己基膦基-3,6-二甲氧基-2 ,4 ,6 -三异丙基-1,1 -联苯)[2-(2-氨基乙基苯基)]钯(II)
  • BRETTPHOS 钯
  • (2-二环己基膦-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯)[2-(2-氨基乙基苯基)]氯化钯(II)
  • 1148148-01-9
  • BrettPhos Palladacycle Gen. 1 Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)
  • (2-Dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II)chloride,BrettPhosPalladacycleGen.1
  • (II) Chloro[2-(dicyclohexylphosphino)-3
  • Chloro[2-(dicyclohexylphosphino)-2’,4’,6’-triisopropyl-3,6-dimethoxybiphenyl][2-(2-aminoethyl)phenyl]palladium(II)
  • BrettPhos Pd G1 MTBE adduct
  • Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)
  • chloro-(2-phenylethylamino)palladium
  • BrettPhos Pd G1
  • BrettPhos precatalyst
  • BrettPhos Palladacycle
  • BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct
  • dicyclohexyl-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane
  • [2-(2-aminoethyl)phenyl]palladium(1+)
  • Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II) [BrettPhos Palladacycle]
  • (SP-4-4)-[2-[2-(Amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP]palladium
  • BrettPhos Pd G1 / Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)
  • Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-...
  • Chloro[2-(dicyclohexylphosphino)-2',4',6'-triisopropyl-3,6-dimethoxybiphenyl][2-(2-aminoethyl)phenyl]palladium(II)
  • Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP]-, (SP-4-4)-
  • Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) / BrettPhos Pd G1
  • Chloride (2-dicyclohexylphosphino-3,6-dimethoxy-2 ', 4', 6 '- triisopropyl-1,1' - biphenyl) [2 - (2-aminoethyl phenyl)] palladium (II)
  • BrettPhos Palladacycle Gen. 1
  • CHLORO[2-(DICYCLOHEXYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL][2-(2-AMINOETHYL)PHENYL]PALLADIUM(II),MIN.98%[BRETTPHOSPALLADACYCLEGEN.1]
  • Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-amino
  • Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(ii)
  • Dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine-(2-(2-aminoethyl)phenyl)palladium(II) chloride
  • (BrettPhos) palladium(II) phenethylamine chloride
  • Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-Minoethyl)phenyl]palladiuM(II),Min.98%[BrettPhosPalladacycle]