ChemicalBook > CAS DataBase List > BrettPhosPalladacycle
BrettPhosPalladacycle
BrettPhosPalladacycle
- CAS No.1148148-01-9
- Chemical Name:BrettPhosPalladacycle
- CBNumber:CB52614378
- Molecular Formula:C43H63ClNO2PPd
- Formula Weight:798.83
- MOL File:1148148-01-9.mol
BrettPhosPalladacycle Property
- Melting point 198-204 °C
- form Powder
- color white
- UNSPSC Code 12161600
- NACRES NA.22
Safety
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H315-H319-H335
- Precautionary statements P261-P305+P351+P338
BrettPhosPalladacycle Price
More Price(5)
- Brand: Sigma-Aldrich
- Product number: 718750
- Product name : BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
- Purity: may contain up to 1 mole equivalent of MTBE, 97%
- Packaging: 100MG
- Price: ₹8469.3
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 718750
- Product name : BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
- Purity: may contain up to 1 mole equivalent of MTBE, 97%
- Packaging: 100MG
- Price: ₹8469.3
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 718750
- Product name : BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
- Purity: may contain up to 1 mole equivalent of MTBE, 97%
- Packaging: 1G
- Price: ₹33211.2
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich
- Product number: 718750
- Product name : BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
- Purity: may contain up to 1 mole equivalent of MTBE, 97%
- Packaging: 5G
- Price: ₹97469.1
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 718750
- Product name : BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
- Purity: may contain up to 1 mole equivalent of MTBE, 97%
- Packaging: 5G
- Price: ₹97469.1
- Updated: 2022/06/14
- Buy: Buy
BrettPhosPalladacycle Chemical Properties,Usage,Production
-
Reaction
- Catalyst for cross-coupling reactions using aryl mesylates with electron-deficient anilines.
- Catalyst for rapid C-N bond-forming processes at low catalyst loading.
- Cross-coupling of 3-Bromo-2-aminopyridine with primary amines.
-
Uses
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Catalyst for:- C,N-cross coupling of unprotected 3-halo-2-aminopyridines with primary and secondary amines
- Amination reaction
- N-arylation of aminophenols
- General Description BrettPhos Pd G1 is a Buchwald first generation (G1) palladacycle precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The formation of the active Pd(0) species in the G1 precatalyst is easy to generate, requiring merely a deprotonation with a base. The resulting catalyst is very active, even at temperatures down to ?40 °C, and can be used in a variety of cross-coupling protocols.
-
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
BrettPhosPalladacycle Preparation Products And Raw materials
Raw materials
Preparation Products
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1148148-01-9, BrettPhosPalladacycleRelated Search:
- Chloro(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle] XPhos Pd G3 SPhos Palladacycle Gen. 4 XPhos Pd G4 Xantphos Pd G3 BrettPhos Pd G3 XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct SPhos Pd G2 Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 tBuXPhos Pd G1 XPhos Pd G1
- Pd
- Buchwald Precatalysts Series
- Buchwald Ligands&Precatalysts
- 抑制剂
- 高端化学
- 钯类贵金属催化剂
- 有机中间体
- 氯
- 金属催化剂
- 贵金属催化剂
- 有机膦配体
- C48H74ClNO3PPd
- C43H63ClNO2PPd
- 氯(2-二环己基膦基-3,6-二甲氧基-2,4,6-三异丙基-1,1-联苯)[2-(2-氨基乙基苯基)
- 氯[2-(二环己基膦基)-3,6-二甲氧基-2'',4'',6''-三异丙基-1,1''-联苯苯基] [2-(2-氨基乙基)苯基]钯(II)
- 化合物 DICYCLOHEXYL(2',4',6'-TRIISOPROPYL-3,6-DIMETHOXY-[1,1'-BIPHENYL]-2-YL)PHOSPHINE-(2-(2-AMINOETHYL)PHENYL)PALLADIUM(II) CHLORIDE
- 氯[2-(二环己基膦基)-2',4',6'-三异丙基-3,6-二甲氧基联苯][2-(2-氨乙基)苯基]钯(II)
- 氯[2-(二环己基膦基)-3,6-二甲氧基-2'',4'',6''-三异丙基-1,1''-联苯苯基][2-(2-氨基乙基)苯基]钯(II)[BRETTPHOSPALLADACYCLEGEN.1
- BRETTPHOS PD G1有机钯化合物
- BRETTPHOS PD G1/ (2-二环己基膦-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯)[2-(2-氨基乙基苯基)]氯化钯(II)
- (2-二环己基膦基-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯)[2-(2-氨基乙基苯基)]氯化钯(II)
- BRETTPHOS PD G1,甲基叔丁基醚加合物
- (2-二环己基膦-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯)[2-(2-氨基乙基苯基)]氯化钯(II) BRETTPHOS PALLADACYCLE GEN. 1
- 二环己基(2',4',6'-三异丙基-3,6-二甲氧基-[1,1'-联苯基] -2-基)膦-(2-(2-氨基乙基)苯基)钯(II)氯化物
- 氯(2-二环己基膦基-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯)[2-(2-氨基乙基苯基)]钯(II)
- [2-(二环己基磷)-3,6-甲氧基-2',4',6'-三异丙基-1,1'-联苯][2-(2-氨基乙基)苯]氯化钯
- (2-二环己基膦基-3,6-二甲氧基-2 ,4 ,6 -三异丙基-1,1 -联苯)[2-(2-氨基乙基苯基)]钯(II)
- BRETTPHOS 钯
- (2-二环己基膦-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯)[2-(2-氨基乙基苯基)]氯化钯(II)
- 1148148-01-9
- BrettPhos Palladacycle Gen. 1 Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)
- (2-Dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II)chloride,BrettPhosPalladacycleGen.1
- (II) Chloro[2-(dicyclohexylphosphino)-3
- Chloro[2-(dicyclohexylphosphino)-2’,4’,6’-triisopropyl-3,6-dimethoxybiphenyl][2-(2-aminoethyl)phenyl]palladium(II)
- BrettPhos Pd G1 MTBE adduct
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)
- chloro-(2-phenylethylamino)palladium
- BrettPhos Pd G1
- BrettPhos precatalyst
- BrettPhos Palladacycle
- BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct
- dicyclohexyl-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane
- [2-(2-aminoethyl)phenyl]palladium(1+)
- Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II) [BrettPhos Palladacycle]
- (SP-4-4)-[2-[2-(Amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP]palladium
- BrettPhos Pd G1 / Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-...
- Chloro[2-(dicyclohexylphosphino)-2',4',6'-triisopropyl-3,6-dimethoxybiphenyl][2-(2-aminoethyl)phenyl]palladium(II)
- Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP]-, (SP-4-4)-
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) / BrettPhos Pd G1
- Chloride (2-dicyclohexylphosphino-3,6-dimethoxy-2 ', 4', 6 '- triisopropyl-1,1' - biphenyl) [2 - (2-aminoethyl phenyl)] palladium (II)
- BrettPhos Palladacycle Gen. 1
- CHLORO[2-(DICYCLOHEXYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL][2-(2-AMINOETHYL)PHENYL]PALLADIUM(II),MIN.98%[BRETTPHOSPALLADACYCLEGEN.1]
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-amino
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(ii)
- Dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine-(2-(2-aminoethyl)phenyl)palladium(II) chloride
- (BrettPhos) palladium(II) phenethylamine chloride
- Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-Minoethyl)phenyl]palladiuM(II),Min.98%[BrettPhosPalladacycle]