Chemical Properties
clear colorless to light yellow liquid
Uses
3-Fluorotoluene was used in gas phase selective synthesis of 3-fluorobenzaldehyde. It was used in generation of tolyl cations by chemical ionization in mass spectrometry.
Synthesis Reference(s)
Journal of the American Chemical Society, 72, p. 4809, 1950
DOI: 10.1021/ja01166a506
General Description
A colorless liquid with an aromatic odor. Boiling point 239°C. Flash point 63°F. Density 0.991 g / cm3---may float or sink in water.
Air & Water Reactions
Highly flammable.
Reactivity Profile
3-Fluorotoluene may be incompatible with strong oxidizing and reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Generates toxic fluoride fumes when burned.
Health Hazard
Inhalation causes upper respiratory irritation. Irritating to skin and eyes. May be absorbed through the skin. Prolonged exposure may result in systemic toxic effects. Harmful if swallowed.
Purification Methods
Purify it as for o-fluorotoluene. [Beilstein 5 H 290, 5 III 676, 5 IV 799.]
