ChemicalBook > CAS DataBase List > 1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
- CAS No.59414-23-2
- Chemical Name:1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
- CBNumber:CB5162112
- Molecular Formula:C8H16O2Si
- Formula Weight:172.3
- MOL File:59414-23-2.mol
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE Property
- Boiling point 68-69 °C14 mm Hg(lit.)
- Density 0.885 g/mL at 25 °C(lit.)
- refractive index n
20/D 1.454(lit.) - Flash point 113 °F
- storage temp. 2-8°C
- solubility insol H2O; sol most organic solvents
- form Liquid
- color Clear light yellow to brown
- Merck 14,6001
- CAS DataBase Reference 59414-23-2(CAS DataBase Reference)
- FDA UNII 29026V137P
- EPA Substance Registry System Silane, [(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl- (59414-23-2)
Safety
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H226-H315-H319
- Precautionary statements P210-P233-P240-P241+P242+P243-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P370+P378-P403+P235-P501
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE Price
More Price(2)
- Brand: TCI Chemicals (India)
- Product number: M0759
- Product name : 1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene
- Purity: min. 95.0 %
- Packaging: 5ML
- Price: ₹11700
- Updated: 2022/05/26
- Buy: Buy
- Brand: TCI Chemicals (India)
- Product number: M0759
- Product name : 1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene
- Purity: min. 95.0 %
- Packaging: 25ML
- Price: ₹48500
- Updated: 2022/05/26
- Buy: Buy
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE Chemical Properties,Usage,Production
- Chemical Properties CLEAR LIGHT YELLOW TO BROWN LIQUID
- Uses 1-Methoxy-3-trimethylsilyloxy-1,3-butadiene is used as a highly reactive diene for Diels-Alder reactions and hetero-Diels-Alder reactions.
-
Preparation
1-Methoxy-3-trimethylsilyloxy-1,3-butadiene was originally prepared from 4-Methoxy-3-buten-2-one with Chlorotrimethylsilane-Triethylamine-Zinc Chloride in benzene as shown below (68% yield, eq 1). At the present time, the most efficient method is to use TMSCl-Lithium Bromide-Et3N in THF (91%).
- storage 1-Methoxy-3-trimethylsilyloxy-1,3-butadiene can be kept in a stoppered container without appreciable decomposition, but it is extremely moisture sensitive.
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE Preparation Products And Raw materials
Raw materials
Preparation Products
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59414-23-2, 1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENERelated Search:
- Vinylsilanes, Allylsilanes
- Synthetic Organic Chemistry
- Si-O Compounds
- Silicon Compounds (for Synthesis)
- Si (Classes of Silicon Compounds)
- Monoalkoxysilanes
- 化学试剂
- 高端化学
- 试剂和补充物
- 有机硅
- Oxygen Compounds
- Organic Building Blocks
- Enol Ethers
- Vinylsilanes, Allylsilanes
- Monoalkoxysilanes
- Silicon Compounds (for Synthesis)
- Si (Classes of Silicon Compounds)
- Si-O Compounds
- Building Blocks
- C8H16O2Si
- (4-甲氧基丁-1,3-二烯-2-基)氧基]三甲基硅烷
- 1-METHOXY-3-(TRIMETHYLSILYLOXY)-1,3-BUTADIENE 1-甲氧基-3-(三甲基硅氧基)-1,3-丁二烯
- 1-甲氧基-3-三甲基硅氧基-1,3-丁二烯
- 1-将甲氧基-3-(三甲基硅氧基)-1,3-丁二烯
- 59414-23-2
- 1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene>
- Silane, [(3-methoxy-1-methylene-2-propen-1-yl)oxy]trimethyl-
- 4-Methoxy-1,3-butadiene-2-yloxytrimethylsilane
- 3-(Trimethylsilyloxy)-1-methoxy-1,3-butadiene
- (3-Methoxy-1-methyleneallyloxy)trimethylsilane
- (3Z)-4-METHOXYBUTA-1,3-DIEN-2-YL]OXY-TRIMETHYL-SILANE
- 1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene, GC 90%
- 1-METHOXY-3-TRIMETHYLSILYLOXY-1,3-BUTADIENE
- 1-METHOXY-3-(TRIMETHYLSILOXY)BUTADIENE
- 1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
- Silane, [(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl-
- TRANS-1-METHOXY-3-(TRIMETHYLSILYLOXY)-1,3-BUTADIENE
- [(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl-silan
- ([(2E)-3-Methoxy-1-methylene-2-propenyl]oxy)(trimethyl)silane
- 1-Me-3-(trimEtsilyloxy)-1,3-butadiene
- methyl 3-trimethylsilyloxybuta-1,3-dien-1-yl ether
- DANISHEFSKY'S DIENE
- 1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene,90%
- Trimethyl[(1-methylene-3-methoxy-2-propenyl)oxy]silane
- 4-Methoxy-2-(trimethylsilyloxy)-1,3-butadiene
- 4-Methoxy-2-(trimethylsiloxy)-1,3-butadiene