ChemicalBook > CAS DataBase List > 1-Bromohexane
1-Bromohexane
1-Bromohexane
- CAS No.111-25-1
- Chemical Name:1-Bromohexane
- CBNumber:CB4447030
- Molecular Formula:C6H13Br
- Formula Weight:165.07
- MOL File:111-25-1.mol
1-Bromohexane Property
- Melting point −85 °C(lit.)
- Boiling point 154-158 °C(lit.)
- Density 1.176 g/mL at 25 °C(lit.)
- vapor density 5.7 (vs air)
- vapor pressure <10 mm Hg ( 20 °C)
- refractive index n
20/D 1.448(lit.) - Flash point 135 °F
- storage temp. Store below +30°C.
- solubility <1g/l
- form Liquid
- color Clear
- Water Solubility Immiscible with water.
- BRN 1731290
- Dielectric constant 5.8(24℃)
- Stability Stable. Incompatible with strong oxidizing agents, strong bases. Combustible.
- InChIKey MNDIARAMWBIKFW-UHFFFAOYSA-N
- CAS DataBase Reference 111-25-1(CAS DataBase Reference)
- FDA UNII WVA0FAX7GA
- NIST Chemistry Reference Hexane, 1-bromo-(111-25-1)
- EPA Substance Registry System Hexane, 1-bromo- (111-25-1)
- UNSPSC Code 12352101
- NACRES NA.22
Safety
- Hazard Codes :Xi
- Risk Statements :36/37/38-10
- Safety Statements :26-36-16
- RIDADR :UN 1993 3/PG 3
- WGK Germany :2
- RTECS :MO0925000
- TSCA :Yes
- HazardClass :3
- PackingGroup :III
- HS Code :29033036
- Toxicity :LD50 orally in Rabbit: > 2000 mg/kg
-
NFPA 704:
2 2 0
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H226-H315-H319-H335
- Precautionary statements P210-P233-P240-P241-P303+P361+P353-P305+P351+P338
1-Bromohexane Price
More Price(11)
- Brand: Sigma-Aldrich(India)
- Product number: B68240
- Product name : 1-Bromohexane
- Purity: 98%
- Packaging: 100G
- Price: ₹1959.33
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: B68240
- Product name : 1-Bromohexane
- Purity: 98%
- Packaging: 500G
- Price: ₹5390.85
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: B68240
- Product name : 1-Bromohexane
- Purity: 98%
- Packaging: 1KG
- Price: ₹5618.18
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 8.01603
- Product name : 1-Bromohexane
- Purity: for synthesis
- Packaging: 100ML
- Price: ₹2260
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 8.01603
- Product name : 1-Bromohexane
- Purity: for synthesis
- Packaging: 500ML
- Price: ₹5620.01
- Updated: 2022/06/14
- Buy: Buy
1-Bromohexane Chemical Properties,Usage,Production
-
Chemical nature
1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.
-
Synthesis and reactions
Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.
1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. It reacts with potassium fluoride to give the corresponding fluorocarbons. - Chemical Properties 1-Bromohexane is a colourless liquid organohalide. It is a solvent that is frequently used in grignard reactions. It is also used as Intermediate, for introduction of hexyl group.
- Uses 1-Bromohexane is utilized in the preparation of pharmaceuticals and organic chemicals. It is involved in Grignard reactions as an alkylating agent and in the synthesis of bromo-cyclic compounds.
- Application 1-Bromohexane is a very useful synthetic intermediate,it can be used to react with Mg to prepare Grignard reagents which play an important role in formation of carbon-carbon bond.
-
Synthesis Reference(s)
Chemistry Letters, 7, p. 833, 1978
Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128
Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0 - Purification Methods Shake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]
1-Bromohexane Preparation Products And Raw materials
Raw materials
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- HALOGEN
- CH3CH2CH2CH2CH2CH2Br
- 111251
- CH3CH25Br
- CH2CH24CH2Br
- 溴代正己烷/AR
- 1-溴代正己烷,99%
- 1-溴己烷,99%
- 溴己烷(溴代正己烷 1-溴己烷)
- X**1-溴己烷
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- N-溴己烷
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- 溴代正己烷(1-溴己烷)
- 溴己烷,1-溴己烷,1-溴代正己烷,己基溴,溴代己烷
- 溴己烷(溴代正己烷)