Chemical nature Synthesis and reactions
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1-Bromohexane

Chemical nature Synthesis and reactions
1-Bromohexane Structure
1-Bromohexane
  • CAS No.111-25-1
  • Chemical Name:1-Bromohexane
  • CBNumber:CB4447030
  • Molecular Formula:C6H13Br
  • Formula Weight:165.07
  • MOL File:111-25-1.mol
1-Bromohexane Property
  • Melting point −85 °C(lit.)
  • Boiling point 154-158 °C(lit.)
  • Density 1.176 g/mL at 25 °C(lit.)
  • vapor density 5.7 (vs air)
  • vapor pressure <10 mm Hg ( 20 °C)
  • refractive index n20/D 1.448(lit.)
  • Flash point 135 °F
  • storage temp. Store below +30°C.
  • solubility <1g/l
  • form Liquid
  • color Clear
  • Water Solubility Immiscible with water.
  • BRN 1731290
  • Dielectric constant 5.8(24℃)
  • Stability Stable. Incompatible with strong oxidizing agents, strong bases. Combustible.
  • InChIKey MNDIARAMWBIKFW-UHFFFAOYSA-N
  • CAS DataBase Reference 111-25-1(CAS DataBase Reference)
  • FDA UNII WVA0FAX7GA
  • NIST Chemistry Reference Hexane, 1-bromo-(111-25-1)
  • EPA Substance Registry System Hexane, 1-bromo- (111-25-1)
  • UNSPSC Code 12352101
  • NACRES NA.22
Safety
  • Hazard Codes  :Xi
  • Risk Statements  :36/37/38-10
  • Safety Statements  :26-36-16
  • RIDADR  :UN 1993 3/PG 3
  • WGK Germany  :2
  • RTECS  :MO0925000
  • TSCA  :Yes
  • HazardClass  :3
  • PackingGroup  :III
  • HS Code  :29033036
  • Toxicity :LD50 orally in Rabbit: > 2000 mg/kg
  • NFPA 704:
    2
    2 0
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H226-H315-H319-H335
  • Precautionary statements P210-P233-P240-P241-P303+P361+P353-P305+P351+P338
1-Bromohexane Price More Price(11)
  • Brand: Sigma-Aldrich(India)
  • Product number: B68240
  • Product name : 1-Bromohexane
  • Purity: 98%
  • Packaging: 100G
  • Price: ₹1959.33
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: B68240
  • Product name : 1-Bromohexane
  • Purity: 98%
  • Packaging: 500G
  • Price: ₹5390.85
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: B68240
  • Product name : 1-Bromohexane
  • Purity: 98%
  • Packaging: 1KG
  • Price: ₹5618.18
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 8.01603
  • Product name : 1-Bromohexane
  • Purity: for synthesis
  • Packaging: 100ML
  • Price: ₹2260
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 8.01603
  • Product name : 1-Bromohexane
  • Purity: for synthesis
  • Packaging: 500ML
  • Price: ₹5620.01
  • Updated: 2022/06/14
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1-Bromohexane Chemical Properties,Usage,Production

  • Chemical nature 1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.
    	1-Bromohexane
  • Synthesis and reactions

    Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.
    1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. It reacts with potassium fluoride to give the corresponding fluorocarbons.

  • Chemical Properties 1-Bromohexane is a colourless liquid organohalide. It is a solvent that is frequently used in grignard reactions. It is also used as Intermediate, for introduction of hexyl group.
  • Uses 1-Bromohexane is utilized in the preparation of pharmaceuticals and organic chemicals. It is involved in Grignard reactions as an alkylating agent and in the synthesis of bromo-cyclic compounds.
  • Application 1-Bromohexane is a very useful synthetic intermediate,it can be used to react with Mg to prepare Grignard reagents which play an important role in formation of carbon-carbon bond.
  • Synthesis Reference(s) Chemistry Letters, 7, p. 833, 1978
    Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128
    Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0
  • Purification Methods Shake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]
1-Bromohexane Preparation Products And Raw materials
Raw materials
Preparation Products
Global(404)Suppliers
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1-Bromohexane Spectrum
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