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L(-)-Pipecolinic acid

Description

CAS No.3105-95-1
Chemical Name:L(-)-Pipecolinic acid
CBNumber:CB4393366
Molecular Formula:C6H11NO2
Formula Weight:129.16
MOL File:3105-95-1.mol

L(-)-Pipecolinic acid Property

Melting point 272 °C(lit.)
alpha -27.5 º (c=5, H2O 24 ºC)
Boiling point 239.22°C (rough estimate)
Density 1.1426 (rough estimate)
refractive index -27 ° (C=4, H2O)
storage temp. 2-8°C
solubility Water: Soluble
form Fine Crystalline Powder
pka 2.28(at 25℃)
color White
optical activity [α]25/D 26.4°, c = 1 in H2O
Water Solubility soluble
Merck 14,7458
BRN 81093
InChIKey HXEACLLIILLPRG-YFKPBYRVSA-N
CAS DataBase Reference 3105-95-1(CAS DataBase Reference)
FDA UNII 69374CKB33
UNSPSC Code 12352200
NACRES NA.26

Safety

Hazard Codes :Xi
Risk Statements :36/37/38
Safety Statements :26-36-24/25
WGK Germany :3
TSCA :No
HS Code :29339900

NFPA 704:

	0
2		0

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordWarning
Hazard statements H315-H319-H335
Precautionary statements P302+P352-P305+P351+P338

L(-)-Pipecolinic acid Price More Price(5)

Brand: Sigma-Aldrich(India)
Product number: P2519
Product name : L-Pipecolic acid
Purity: 99% (titration)
Packaging: 100MG
Price: ₹10576.03
Updated: 2022/06/14
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Brand: Sigma-Aldrich(India)
Product number: P2519
Product name : L-Pipecolic acid
Purity: 99% (titration)
Packaging: 250MG
Price: ₹20773.18
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: P2519
Product name : L-Pipecolic acid
Purity: 99% (titration)
Packaging: 1G
Price: ₹42791.23
Updated: 2022/06/14
Buy: Buy

Brand: TCI Chemicals (India)
Product number: P1404
Product name : L-Pipecolic Acid
Purity:
Packaging: 1G
Price: ₹6300
Updated: 2022/05/26
Buy: Buy

Brand: TCI Chemicals (India)
Product number: P1404
Product name : L-Pipecolic Acid
Purity:
Packaging: 5G
Price: ₹6600
Updated: 2022/05/26
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L(-)-Pipecolinic acid Chemical Properties,Usage,Production

Description L-Pipecolinic acid is involved in synaptic transmission in the central nervous system. It is also used as pharmaceutical intermediate. It is a lysine metabolite; defect in its catabolism is involved in hyperpipecolic acidemia, cerebro-hepato-renal syndrome, neonatal onset adrenoleukodystrophy, and infantile Refsum disease. It can be associated with some forms of epilepsy. CRYM, a taxon-specific crystallin protein that also binds thyroid hormones, is involved in the pipecolic acid pathway.
Chemical Properties white to light yellow crystal powde
Uses L-Pipecolinic acid is involved in synaptic transmission in the central nervous system. It is also used as pharmaceutical intermediate.
Uses Pipecolic acid is involved in synaptic transmission in the central nervous system. The l-form occurs in plants.
Definition ChEBI: A pipecolate that is the conjugate acid of L--pipecolic acid.
General Description Occurs in seeds, malt, edible mushrooms, fruits, etc.
Biochem/physiol Actions L-pipecolic acid is implicated in Zellweger syndrome. Pipecolic acid is also a plant defence metabolite. It is a signaling compound essential for systemic acquired resistance (SAR).
Purification Methods It crystallises from water. The (±)-picrate has m 158-159o (from EtOH or C6H6). [Beilstein 22 H 7, 22 III/IV 97, 22/1 V 220.] The R(+)-enantiomer [1723-00-8] has m 277o(dec) and [] D 20 +27o (c 4, H2O), and the S(-)-enantiomer [3105-95-1] has m 277o(dec) and [] D 20 -26o (c 4, H2O).[cf p 603, Beilstein 22 III/IV 96, 22/1 V 220.]