ChemicalBook > CAS DataBase List > Tris(triphenylphosphine)ruthenium(II) chloride
Tris(triphenylphosphine)ruthenium(II) chloride
Tris(triphenylphosphine)ruthenium(II) chloride
- CAS No.15529-49-4
- Chemical Name:Tris(triphenylphosphine)ruthenium(II) chloride
- CBNumber:CB3343551
- Molecular Formula:C54H45Cl2P3Ru
- Formula Weight:958.83
- MOL File:15529-49-4.mol
Tris(triphenylphosphine)ruthenium(II) chloride Property
- Melting point 159 °C
- storage temp. Inert atmosphere,Room Temperature
- solubility Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene
- form Solution
- color Clear
- Water Solubility insoluble
- Sensitive Air & Moisture Sensitive
- Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
- BRN 4935939
- InChI InChI=1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
- InChIKey QUVLSIIMVTXAPD-UHFFFAOYSA-M
- SMILES P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Ru](Cl)Cl
- CAS DataBase Reference 15529-49-4(CAS DataBase Reference)
- UNSPSC Code 12161600
- NACRES NA.22
Safety
- Hazard Codes :Xn
- Risk Statements :20/21/22-20/21
- Safety Statements :36/37-22
- RIDADR :2811
- WGK Germany :3
- TSCA :No
- HS Code :28439000
-
NFPA 704:
1 2 0
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H302+H312+H332
- Precautionary statements P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P501
Tris(triphenylphosphine)ruthenium(II) chloride Price
More Price(6)
- Brand: Sigma-Aldrich(India)
- Product number: 223662
- Product name : Tris(triphenylphosphine)ruthenium(II) dichloride
- Purity: 97%
- Packaging: 1G
- Price: ₹2686.2
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 223662
- Product name : Tris(triphenylphosphine)ruthenium(II) dichloride
- Purity: 97%
- Packaging: 5G
- Price: ₹10644.9
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 223662
- Product name : Tris(triphenylphosphine)ruthenium(II) dichloride
- Purity: 97%
- Packaging: 25G
- Price: ₹45165.9
- Updated: 2022/06/14
- Buy: Buy
- Brand: TCI Chemicals (India)
- Product number: D1997
- Product name : Tris(triphenylphosphine)ruthenium(II) Dichloride
- Purity:
- Packaging: 1G
- Price: ₹3300
- Updated: 2022/05/26
- Buy: Buy
- Brand: TCI Chemicals (India)
- Product number: D1997
- Product name : Tris(triphenylphosphine)ruthenium(II) Dichloride
- Purity:
- Packaging: 5G
- Price: ₹9700
- Updated: 2022/05/26
- Buy: Buy
Tris(triphenylphosphine)ruthenium(II) chloride Chemical Properties,Usage,Production
- Chemical Properties black crystals
- Uses Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System
- Uses suzuki reaction
- Preparation Tris(triphenylphosphine)ruthenium(II) chloride can be prepared by refluxing hydrated Ruthenium(III) Chloride and Triphenylphosphine in ethanol according to the procedure of Wilkinson.
- General Description Tris(triphenylphosphine)ruthenium(II) chloride can be used in the hydrogenation of nitro groups, imines, and ketones, and the selective oxidation of alcohols.
-
reaction suitability
core: ruthenium
reagent type: catalyst
reaction type: C-H Activation
Tris(triphenylphosphine)ruthenium(II) chloride Preparation Products And Raw materials
Raw materials
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15529-49-4, Tris(triphenylphosphine)ruthenium(II) chlorideRelated Search:
- Tricine Tris(hydroxymethyl)aminomethane Ruthenium(III) chloride Ruthenium Tris(triphenylphosphine)rhodiu BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE) TRIPHENYLPHOSPHINE DIBROMIDE BIS-Tris Triphenylphosphine Potassium chloride cis-Bis(triphenylphosphine)platinum(II) chloride Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt Triphenylphosphine oxide Bis(triphenylphosphine)palladium(II) chloride CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Tetrakis(triphenylphosphine)platinum Allylpalladium(II) Chloride Dimer Bis(tri-tert-butylphosphine)palladium(0)
- Metal Complexes
- Homogeneous Catalysts
- Environmentally-friendly Oxidation
- Classes of Metal Compounds
- Catalysts for Organic Synthesis
- metal-phosphine complexes
- Ru
- Metal Compounds
- chemical reaction,pharm,electronic,materials
- Transition Metal Compounds
- Transition Metal Complexes (Environmentally-friendly Oxidation)
- Synthetic Organic Chemistry
- Ru (Ruthenium) Compounds
- 医用原料
- 化学试剂
- 高端化学
- 原料药
- 化工原料
- 钌 系列
- 化工中间体
- 中间体-有机中间体
- 有机金属催化剂
- 医药原料
- 其他生化试剂
- 贵金属
- 含钌催化剂
- 石油精制用催化剂
- 催化剂及助剂
- 金属催化剂
- 金属有机物
- 金属化合物
- 膦配体
- 有机贵重金属
- 催化和无机化学
- 贵金属催化剂
- 有机贵金属
- 铑催化剂
- 医药中间体
- 钌
- 通用试剂
- Ru (Ruthenium) Compounds
- Transition Metal Complexes (Environmentally-friendly Oxidation)
- Metal Complexes
- Environmentally-friendly Oxidation
- Homogeneous Catalysts
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Transition Metal Compounds
- Ru Catalysts
- Catalysis and Inorganic Chemistry
- 3C18H15PCl2Ru
- C54H45P3Cl2Ru
- RuCl2PC6H533
- RuCl2PC5H634
- C6H53P3RuCl2
- RuCl2PPh33
- C54H45Cl2P3Ru
- 15529-45-4