ChemicalBook > CAS DataBase List > 1,1-Diphenylethylene
1,1-Diphenylethylene
1,1-Diphenylethylene
- CAS No.530-48-3
- Chemical Name:1,1-Diphenylethylene
- CBNumber:CB1853742
- Molecular Formula:C14H12
- Formula Weight:180.25
- MOL File:530-48-3.mol
1,1-Diphenylethylene Property
- Melting point 6 °C (lit.)
- Boiling point 270-271 °C (lit.)
- Density 1.021 g/mL at 25 °C (lit.)
- refractive index n
20/D 1.608(lit.) - Flash point 221 °F
- storage temp. 2-8°C
- form Liquid
- color Clear colorless to golden
- Water Solubility Miscible with methanol, chloroform and ether. Insoluble in water.
- Merck 14,3323
- BRN 1099062
- InChIKey ZMYIIHDQURVDRB-UHFFFAOYSA-N
- CAS DataBase Reference 530-48-3(CAS DataBase Reference)
- FDA UNII BX0L5B6LLL
- NIST Chemistry Reference Ethylene, 1,1-diphenyl-(530-48-3)
- EPA Substance Registry System Benzene, 1,1'-ethenylidenebis- (530-48-3)
- UNSPSC Code 12352100
- NACRES NA.22
Safety
- Safety Statements :23-24/25
- RIDADR :UN 3082 9 / PGIII
- WGK Germany :3
- TSCA :Yes
- HS Code :29029090
-
NFPA 704:
0 0 0
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H411
- Precautionary statements P273-P391-P501
1,1-Diphenylethylene Price
More Price(10)
- Brand: Sigma-Aldrich(India)
- Product number: D206806
- Product name : 1,1-Diphenylethylene
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- Updated: 2022/06/14
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- Brand: Sigma-Aldrich(India)
- Product number: D206806
- Product name : 1,1-Diphenylethylene
- Purity: 97%
- Packaging: 10G
- Price: ₹2866.73
- Updated: 2022/06/14
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- Brand: Sigma-Aldrich(India)
- Product number: D206806
- Product name : 1,1-Diphenylethylene
- Purity: 97%
- Packaging: 25G
- Price: ₹5897.85
- Updated: 2022/06/14
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- Product number: ALF-A14434-30
- Product name : 1,1-Diphenylethylene, 98%
- Purity:
- Packaging: 250g
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- Updated: 2022/05/26
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- Product number: ALF-A14434-22
- Product name : 1,1-Diphenylethylene, 98%
- Purity:
- Packaging: 100g
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1,1-Diphenylethylene Chemical Properties,Usage,Production
- Chemical Properties Clear colorless to golden liquid
- Uses 1,1-Diphenylethylene is used in the preparation of 2-chloro-1,1-diphenyl-ethene by reacting with benzeneseleninyl chloride and aluminum(III) chloride as reagents. It acts as an intermediate in organic synthesis as well as in pharmaceuticals.
- Synthesis Reference(s) The Journal of Organic Chemistry, 26, p. 4199, 1961 DOI: 10.1021/jo01069a005
- Reactivity Profile 1,1-Diphenylethylene (DPE) is well known for its inability to undergo homopolymerization but can participate in radical copolymerizations. The participation of DPE in radical polymerization leads to the formation of stable DPE radicals by resonance stabilization of the radical by the two phenyl groups and a strong steric hindrance for the addition of any other monomer. Thus, DPE has drastic effects on radical polymerizati[1].
- Synthesis 1,1-Diphenylethylene can be prepared by the action of alcoholic potassium hydroxide on unsymmetrical diphenylchloroethane; by the action of aluminum chloride on benzene and tribromoethylene; and by dehydration of the carbinol which can be prepared by the action of methylmagnesium iodide on benzophenone, or phenylmagnesium bromide on acetophenone or ethyl acetate.
- References [1] Sophie Viala . “Structural control in radical polymerization with 1,1-diphenylethylene. 1. Copolymerization of 1,1-diphenylethylene with methyl methacrylate.” Polymer 43 26 (2002): Pages 7231-7241.
1,1-Diphenylethylene Preparation Products And Raw materials
Raw materials
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- 1,1-distyrene
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- DKSI010
- 1-BROMO-4-(DIETHOXYMETHYL)BENZENE
- 1,1-DIPHENYLETHENE
- Ethene-1,1-diyldibenzene
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- DDNU
- 1,1-Diphenylethylene ISO 9001:2015 REACH
- 1,1-Diphenylethylene (stabilized with HQ)>
- 1,1-Diphenylethylene, 97.5%, for synthesis
- Clemastine Fumarate Impurity 2
- 1,1-Diphenylethylene, 97.5%