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N-Methyl-4-nitroaniline

Uses Biodegradation

CAS No.100-15-2
Chemical Name:N-Methyl-4-nitroaniline
CBNumber:CB1387643
Molecular Formula:C7H8N2O2
Formula Weight:152.15
MOL File:100-15-2.mol

N-Methyl-4-nitroaniline Property

Melting point 149-151 °C(lit.)
Boiling point 294.61°C (rough estimate)
Density 1.2010
vapor density 5.25 (vs air)
refractive index 1.6276 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Solid
pka 0.56±0.12(Predicted)
color Yellow to Very Dark Yellow
Water Solubility <0.1 g/100 mL at 19 ºC
BRN 637920
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey XIFJZJPMHNUGRA-UHFFFAOYSA-N
CAS DataBase Reference 100-15-2(CAS DataBase Reference)
FDA UNII J836WLV9BW
NIST Chemistry Reference Benzenamine, N-methyl-4-nitro-(100-15-2)
EPA Substance Registry System N-Methyl-p-nitroaniline (100-15-2)
UNSPSC Code 12352100
NACRES NA.22

Safety

Hazard Codes :T,Xi
Risk Statements :23/24/25-33-36/37/38
Safety Statements :28-36/37/39-45-26
RIDADR :2811
WGK Germany :3
Hazard Note :Highly Toxic/Irritant
TSCA :Yes
HazardClass :6.1
PackingGroup :III
HS Code :29214200

NFPA 704:

	1
3		0

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordDanger
Hazard statements H301+H311+H331-H373-H412
Precautionary statements P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P314

N-Methyl-4-nitroaniline Price More Price(2)

Brand: Sigma-Aldrich(India)
Product number: 269638
Product name : N-Methyl-4-nitroaniline
Purity: 97%
Packaging: 25G
Price: ₹5412.5
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 269638
Product name : N-Methyl-4-nitroaniline
Purity: 97%
Packaging: 100G
Price: ₹18943.75
Updated: 2022/06/14
Buy: Buy

N-Methyl-4-nitroaniline Chemical Properties,Usage,Production

Uses N-methyl-4-nitroaniline is a stabilizer for gunpowder, a desensitizing agent for molten cast explosive TNAZ, a widely used organic intermediate, and N-methyl-4-nitroaniline can be used as a reference substance by its polarizing properties.
N-methyl-4-nitroaniline is an attractive candidate for its appealing capability to retain the nitrogen oxides, good thermal stability, and facile synthesis from abundant and inexpensive starting materials.
Biodegradation N-Methyl-4-nitroaniline is used as an additive to lower the melting temperature of energetic materials in the synthesis of insensitive explosives. Although the biotransformation of N-Methyl-4-nitroaniline under anaerobic condition has been reported, its aerobic microbial degradation has not been documented yet. A soil microcosms study showed the efficient aerobic degradation of N-Methyl-4-nitroaniline by the inhabitant soil microorganisms.
Chemical Properties brownish-yellow crystalline powder
Uses N-Methyl-4-nitroaniline is a versatile reactant used in the synthesis of oxindoles using Pd-catalyzed cyclization of chloroacetanilides.
General Description Brownish-yellow prisms with violet reflex (from ethanol) or yellow powder.
Air & Water Reactions N-Methyl-4-nitroaniline may be sensitive to prolonged exposure to air. Insoluble in water.
Reactivity Profile N-Methyl-4-nitroaniline has a vigorous exothermic reaction with carbaryl sulfate when heated above 167° F.
Fire Hazard Flash point data for N-Methyl-4-nitroaniline are not available; however, N-Methyl-4-nitroaniline is probably combustible.
Purification Methods Crystallise the aniline from aqueous EtOH. [Beilstein 12 H 714.]