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Tris(1-Chloro-2-Propyl) Phosphate

CAS No.13674-84-5
Chemical Name:Tris(1-Chloro-2-Propyl) Phosphate
CBNumber:CB0221470
Molecular Formula:C9H18Cl3O4P
Formula Weight:327.57
MOL File:13674-84-5.mol

Tris(1-Chloro-2-Propyl) Phosphate Property

Melting point -39.9°C
Boiling point 270°C
Density 1.28
refractive index 1.460～1.466 (20℃/D)
Flash point -218 °C
storage temp. Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form liquid
color Clear Colourless
Odor mild odor
Water Solubility <0.1 g/100 mL at 19.5 ºC
BRN 1842347
Stability Moisture Sensitive
InChIKey KVMPUXDNESXNOH-UHFFFAOYSA-N
CAS DataBase Reference 13674-84-5(CAS DataBase Reference)
FDA UNII CRT22GFY70
NIST Chemistry Reference 2-Propanol, 1-chloro-, phosphate (3:1)(13674-84-5)
EPA Substance Registry System Tris(1-chloro-2-propyl) phosphate (13674-84-5)
UNSPSC Code 41116107
NACRES NA.24

Safety

Hazard Codes :Xn
Risk Statements :22-37
WGK Germany :1
RTECS :TC9000000
Hazardous Substances Data :13674-84-5(Hazardous Substances Data)

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordWarning
Hazard statements H302
Precautionary statements P301+P312+P330

Tris(1-Chloro-2-Propyl) Phosphate Price More Price(1)

Brand: Sigma-Aldrich(India)
Product number: 32952
Product name : TCPP, mixture of isomers
Purity: PESTANAL?, analytical standard
Packaging: 100MG
Price: ₹18207.65
Updated: 2022/06/14
Buy: Buy

Tris(1-Chloro-2-Propyl) Phosphate Chemical Properties,Usage,Production

Chemical Properties Tris(2-chloro-1-methylethyl) phosphate is clear colorless oily liquid with high water solubility and low lipophilicity (as indicated by logKOW). This substance ismanufactured as a reactionmixture, which contains four isomers. It is the primary isomer in the mixture at 50–85% weight/weight (w/w), followed by bis(1- chloro-2-propyl)-2-chloropropyl phosphate [15–40% (w/w); CASRN: 76025-08-6], bis(2-chloropropyl)-1-chloro-2-propyl phosphate [<15% (w/w); CASRN: 76649-15-5], and tris(2- chloropropyl) phosphate [<1% (w/w); CASRN: 6145-73-9] (EURAR, 2008).
Uses Tris(1-chloro-2-propyl) Phosphate is a flame retardant of low hydrolytic stability, used in polyurethane (PU) rigid and flexible foam, PVC, EVA, phenolics and epoxy resin.
Definition ChEBI: Tris(1-chloropropan-2-yl) phosphate is a trialkyl phosphate.
General Description Clear colorless viscous liquid. Tris(2-chloroisopropyl) Phosphate(TCPP), mixture of isomers is suitable for use in environmental and food residue analysis. It is a mixture of isomers, composition may vary, typical composition: main isomer tris(1-chloro-2-propyl) phosphate 66%, minor components: bis(1-chloro-2-propyl) (2-chloropropyl) phosphate and (1-chloro-2-propyl) bis(2-chloropropyl) phosphate.
Air & Water Reactions Insoluble in water.
Reactivity Profile Phosphoric acid tris(2-chloro-1-methylethyl) ester may hydrolyze under acidic or alkaline conditions.
Health Hazard ACUTE/CHRONIC HAZARDS: When heated to decomposition Phosphoric acid tris(2-chloro-1-methylethyl) ester emits very toxic fumes.
Fire Hazard Phosphoric acid tris(2-chloro-1-methylethyl) ester is probably combustible.
Toxicology Tris(1-Chloro-2-Propyl) Phosphate (TCPP) is considered a suspected carcinogenic, suspected reprotoxic, and suspected PBT (persistent, bioaccumulative and toxic) and is a potential endocrine disruptor (ECHA, 2019). Thus, the presence of TCPP in the receiving water can affect aquatic organisms and potentially affect human health.