Methyl methanesulfonate Structure

Methyl methanesulfonate

Chemical Properties

Melting point 20°C
Boiling point 202-203 °C(lit.)
Density  1.3 g/mL at 25 °C(lit.)
vapor pressure  0.8 hPa (59 °C)
refractive index  n20/D 1.414(lit.)
Flash point 220 °F
storage temp.  Store below +30°C.
solubility  200g/l
form  Liquid
color  Colorless to pale yellow
Water Solubility  200 g/L (20 ºC)
Merck  14,6097
BRN  1098586
Henry's Law Constant 2.5×100 mol/(m3Pa) at 25℃, HSDB (2015)
Stability Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, strong bases.
InChI 1S/C2H6O3S/c1-5-6(2,3)4/h1-2H3
InChIKey MBABOKRGFJTBAE-UHFFFAOYSA-N
SMILES COS(C)(=O)=O
CAS DataBase Reference 66-27-3(CAS DataBase Reference)
FDA UNII AT5C31J09G
Proposition 65 List Methyl Methanesulfonate
IARC 2A (Vol. 7, Sup 7, 71) 1999
NIST Chemistry Reference Methanesulfonic acid, methyl ester(66-27-3)
EPA Substance Registry System Methyl methanesulfonate (66-27-3)
UNSPSC Code 41116107
NACRES NA.24

Safety

Symbol(GHS) Skull and Crossbones (GHS06)Health Hazard (GHS08)Environment (GHS09)
Signal wordDanger
Hazard statements H301-H315-H319-H334-H340-H351-H361fd-H373-H411
Precautionary statements P201-P273-P301+P310-P302+P352-P304+P340+P312-P305+P351+P338
Hazard Codes  T
Risk Statements  45-22-36/37/38-68
Safety Statements  53-26-45-36/37/39
RIDADR  UN 2810 6.1/PG 3
WGK Germany  3
RTECS  PB2625000
F  21
TSCA  TSCA listed
HS Code  2905 19 00
HazardClass  6.1(b)
PackingGroup  III
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Oral
Aquatic Chronic 2
Carc. 2
Eye Irrit. 2
Muta. 1B
Repr. 2
Skin Irrit. 2
Skin Sens. 1
STOT RE 2 Inhalation
Hazardous Substances Data 66-27-3(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 225 mg/kg
NFPA 704:
1
3 0

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