[Ir(dtbbpy)(ppy)2][PF6]

Reaction

1. This Iridium catalyst is used in the synthesis of β-amidovinyl sulfones via visible-light photoredox catalysis.
2. Numerous uses of this photoredox catalyst are reported

Uses

• Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
• Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
• Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
• Aryl-alkyl C?C reductive cross-coupling reactions.