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932-31-0

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Identification

Name
O-TOLYLMAGNESIUM BROMIDE
CAS
932-31-0
Synonyms
o-Tolylbromomagnesium
bromo-o-tolylmagnesium
O-TOLYLMAGNESIUM BROMIDE
2-Methylphenylbromomagnesium
o-TolylMagnesiuM BroMide 
magnesium methylbenzene bromide
Bromo(2-methylphenyl) magnesium
2-METHYLPHENYLMAGNESIUM BROMIDE
MagnesiuM,broMo(2-Methylphenyl)-
o-tolylmagnesium bromide solution
O-TOLYLMAGNESIUM BROMIDE: 19% IN THF, 1M/L
2-Tolylmagnesium bromide 2M solution in DEE
2-Tolylmagnesium bromide 0.5M solution in THF
o-Tolylmagnesium bromide, 2M solution in diethyl ether
o-Tolylmagnesium bromide solution 2.0 in diethyl ether
o-Tolylmagnesium bromide solution 2.0M in diethyl ether
o-TolylMagnesiuM BroMide, 1.0 M solution in THF, SpcSeal
O-TOLYLMAGNESIUM BROMIDE, 2.0M SOLUTION IN DIETHYL ETHER
o-Tolylmagnesium Bromide (19% in Tetrahydrofuran, ca. 1mol/L)
o-Tolylmagnesium bromide, 2M solution in diethyl ether, AcroSeal
o-TolylMagnesiuM broMide, 2.0 M solution in diethyl ether, J&KSeal
o-TolylMagnesiuM broMide, 2.0 M solution in diethyl ether, SpcSeal
o-TolylMagnesiuM BroMide (ca. 17% in Tetrahydrofuran, ca. 0.9Mol/L)
EINECS(EC#)
213-250-2
Molecular Formula
C7H7BrMg
MDL Number
MFCD00010350
MOL File
932-31-0.mol
Molecular Weight
195.34

Chemical Properties

density 
1.013 g/mL at 25 °C

Fp 
−40 °F

form 
Solution
color 
Gray to brown
InChIKey
DVXDIGKNJYSMFM-UHFFFAOYSA-M
CAS DataBase Reference
932-31-0

Hazard Information

Chemical Properties
Yellow to brown liquid
Uses
2-Tolylmagnesium Bromide is an intermediate used in the synthesis of 13-Fluorodibenzo[a,i]pyrene (F588440), which is a polycyclic aromatic hydrocarbon (PAH) thus potentially exhibiting carcinogenic properties through activation of P450 mono-oxygenase enzymes. Also, it has unique electrical and optical properties due to being a conjugated macromolecule.

Safety Data

Hazard Codes 
F+,C,F
Risk Statements 
12-14-20/21/22-34-40-67-22-19-11
Safety Statements 
16-26-33-36/37/39-45
RIDADR 
UN 3399 4.3/PG 1

WGK Germany 
3
HazardClass 
3/8
PackingGroup 
II
HS Code 
29319090
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