ChemicalBook CAS DataBase List 7789-18-6

7789-18-6

Name	Cesium nitrate
CAS	7789-18-6
EINECS(EC#)	200-272-2
Molecular Formula	CsNO3
MDL Number	MFCD00008131
Molecular Weight	194.91
MOL File	7789-18-6.mol

Chemical Properties

Appearance	colourless crystals
Melting point	414 °C (lit.)
Boiling point	233 °C
bulk density	1500kg/m3
density	3.685 g/mL at 25 °C(lit.)
refractive index	1.55
storage temp.	2-8°C
solubility	H₂O: 100 mg/mL
form	powder
color	<5 (200 mg/mL)(APHA)
Specific Gravity	3.685
PH	5.0-7.5 (50g/l, H2O, 20℃)
Stability:	Stable, but hygroscopic. Oxidizer. Contact with combustible material may cause fire. Decomposes at high temperatures. Incompatible with strong reducing agents, alcohols, organic materials, aluminium.
Water Solubility	9.16 g/100 mL (0 ºC)
Sensitive	Hygroscopic
Merck	14,2015
Exposure limits	ACGIH: TWA 2 ppm; STEL 4 ppm OSHA: TWA 2 ppm(5 mg/m3) NIOSH: IDLH 25 ppm; TWA 2 ppm(5 mg/m3); STEL 4 ppm(10 mg/m3)
InChI	1S/Cs.NO3/c;2-1(3)4/q+1;-1
InChIKey	NLSCHDZTHVNDCP-UHFFFAOYSA-N
SMILES	[Cs+].[O-]N(=O)=O
CAS DataBase Reference	7789-18-6(CAS DataBase Reference)
EPA Substance Registry System	7789-18-6(EPA Substance)

Safety Data

Hazard Codes	O,Xi
Risk Statements	R8:Contact with combustible material may cause fire. R36/37/38:Irritating to eyes, respiratory system and skin . less more
Safety Statements	S22:Do not breathe dust . S24/25:Avoid contact with skin and eyes . S17:Keep away from combustible material . less more
RIDADR	UN 1451 5.1/PG 3
WGK Germany	2
RTECS	MB7600000
F	3
TSCA	Yes
HS Code	2834 29 80
REACH Registrations	Active
HazardClass	5.1
PackingGroup	III
Storage Class	5.1A - Strongly oxidizing hazardous materials
Hazard Classifications	Acute Tox. 4 Oral Ox. Sol. 1 Repr. 2
Safety Profile	Moderately toxic by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also CESIUM and NITRATES. less more
Toxicity	LD50 i.p. in rats: 1.2 g/kg (Cochran) less more

Hazard Information

General Description

CESIUM NITRATE(7789-18-6) is a colorless, glittering crystalline solid. CESIUM NITRATE(7789-18-6) is soluble in water. CESIUM NITRATE(7789-18-6) is a strong oxidizing material and may burst into flames on contact with organic materials.

Reactivity Profile

Mixtures of metal/nonmetal nitrates with alkyl esters may explode owing to the formation of alkyl nitrates. Mixtures a nitrate with phosphorus, tin (II) chloride, or other reducing agents may react explosively [Bretherick 1979 p. 108-109].

Air & Water Reactions

Water soluble.

Hazard

Dangerous, may ignite organic materials on contact.

Health Hazard

Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.

Chemical Properties

colourless crystals

Uses

A reagent used as a colorant and an oxidizer in pyrotechnic compositions

Uses

Cesium nitrate prisms are used in infrared spectroscopy, x-ray phosphors and scintillation counters. It is a precursor material for the synthesis of cesium nitratocuprate and cesium salts. Cesium nitrate doped on carbon-based ruthenium catalyst plays an important role in synthesis of ammonia.

Uses

preparation of other Cs salts.

Uses

Used in the synthesis of cesium nitratocuprate, Cs2[Cu(NO3)4], which crystallizes in a square-planar coordination around the Cu center.1

Flammability and Explosibility

Nonflammable

Purification Methods

It crystallises from water (0.6mL/g) between 100o and 0o. After 1 crystallisation of 99.9% grade salt, it had K, Na and Se at 0.8, 0.4 and 0.2 ppm respectively.

7789-18-6

Chemical Properties

Safety Data

Hazard Information

General Description

Reactivity Profile

Air & Water Reactions

Hazard

Health Hazard

Fire Hazard

Chemical Properties

Uses

Uses

Uses

Uses

Flammability and Explosibility

Purification Methods

Material Safety Data Sheet(MSDS)

Questions And Answer

Description

References

Spectrum Detail

Well-known Reagent Company Product Information