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1-Chloro-1-nitrosocyclohexane is used to electrophilic [NH2+] for alkenes and can function as a dienophile for [4 + 2] reactions.

Preparative Methods of 1-Chloro-1-nitrosocyclohexane: the most commonly used method is the reaction of cyclohexanone oxime with a chlorinating agent such as t-Butyl Hypochlorite in trichlorofluoromethane (eq 1).^[1]

1. Luttke, W.; Diekman, H. AG(E) 1968, 7, 387.