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554-84-7

Supplier Related Products Identification Chemical Properties Safety Data Raw materials And Preparation Products Hazard Information Material Safety Data Sheet(MSDS) Spectrum Detail Well-known Reagent Company Product Information

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Identification

Name
3-Nitrophenol
CAS
554-84-7
Synonyms
3-Hydroxy-1-nitrobenzene
3-NITROPHENOL
M-NITROPHENOL
M-NITROPHENOL INDICATOR
1-Hydroxy-3-nitrobenzene
3-Hydroxynitrobenzene
3-Hydroxy-nitrobenzene
3-hydroxynitrobenzene[qr]
3-nitro-pheno
crumpleather-lastingdressing[qr]
meta-Nitrophenol
m-Hydroxynitrobenzene
m-hydroxynitrobenzene[qr]
m-Nitrofenol
m-nitro-pheno
m-nitrophenol(3-nitrophenol)
m-nitrophenol[qr]
Phenol, m-nitro-
Phenol,3-nitro-
phenol,3-nitro-[qr]
EINECS(EC#)
209-073-5
Molecular Formula
C6H5NO3
MDL Number
MFCD00007240
Molecular Weight
139.11
MOL File
554-84-7.mol

Chemical Properties

Appearance
yellow to brown crystalline powder
mp 
89-95 °C

bp 
194 °C70 mm Hg(lit.)

density 
1,49 g/cm3
Fp 
102°C
Water Solubility 
13.5 g/L (25 ºC)
Merck 
14,6619
Detection Methods
HPLC
BRN 
1907946
CAS DataBase Reference
554-84-7(CAS DataBase Reference)
NIST Chemistry Reference
Phenol, 3-nitro-(554-84-7)
EPA Substance Registry System
554-84-7(EPA Substance)

Safety Data

Hazard Codes 
Xn,Xi
Risk Statements 
R22:Harmful if swallowed.
R38:Irritating to the skin.
R41:Risk of serious damage to eyes.
R36/37/38:Irritating to eyes, respiratory system and skin .
R33:Danger of cumulative effects.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S22:Do not breathe dust .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
RIDADR 
UN 1663 6.1/PG 3

WGK Germany 
3

RTECS 
SM1925000


8
Hazard Note 
Harmful/Irritant
HazardClass 
6.1
PackingGroup 
III
HS Code 
29089000
Safety Profile
Poison by ingestion, subcutaneous, and intraperitoneal routes. Moderately toxic by skin contact. A skin and severe eye irritant. When heated to decomposition it emits toxic fumes of NOx. See also other nitrophenol entries.
Hazardous Substances Data
554-84-7(Hazardous Substances Data)

Raw materials And Preparation Products

Raw materials
3-Nitroaniline
Preparation Products
m-Anisidine-->2,5-DINITROPHENOL-->3,5-DINITROPHENOL

Hazard Information

General Description
Colorless to pale yellow crystalline solid. Sinks in and mixes with water.
Reactivity Profile
M-NITROPHENOL(554-84-7) is a light-yellow, crystalline material, toxic and irritant. When heated to decomposition M-NITROPHENOL(554-84-7) emits toxic fumes of oxides of nitrogen [Lewis, 3rd ed., 1993, p. 941]. Phenols do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has Ka = 1.3 x 10^[-10]). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases.
Air & Water Reactions
Water insoluble.
Hazard
Toxic by ingestion.
Health Hazard
INHALATION: Inhalation or ingestion causes headaches, drowsiness, nausea, and blue color in lips, ears, and finger nails (cyanosis). EYES: Contact with eyes causes irritation. SKIN: Can be absorbed through intact skin to give same symptoms as for inhalation.
Fire Hazard
Special Hazards of Combustion Products: Dangerous toxic fumes of NO x

Material Safety Data Sheet(MSDS)

Spectrum Detail

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