110-01-0

Name Tetrahydrothiophene
CAS 110-01-0
EINECS(EC#) 203-728-9
Molecular Formula C4H8S
MDL Number MFCD00005476
Molecular Weight 88.17
MOL File 110-01-0.mol

Chemical Properties

Appearance colourless liquid
Melting point  -96 °C (lit.)
Boiling point  119 °C (lit.)
density  1 g/mL at 25 °C(lit.)
vapor pressure  18 mm Hg ( 25 °C)
refractive index  n20/D 1.504(lit.)
Fp  55 °F
storage temp.  Flammables area
solubility  immiscible
form  liquid
color  Colorless to Almost colorless
Specific Gravity 1.002 (20/4℃)
Odor Smells of rotting eggs
PH 7 (H2O, 20℃)
Stability: Highly flammable. Vapour-air mixtures explosive in some proportions; note low flash point and fairly wide explosion limit range. Heavier than air, so potentially explosive mixtures may travel considerable distances to source of ignition.
explosive limit 1.1-12.1%(V)
Odor Threshold 0.00062ppm
Odor Type sulfurous
Water Solubility  immiscible
Merck  14,9218
BRN  102392
Henry's Law Constant 2.2×10-3 mol/(m3Pa) at 25℃, Yaws et al. (2003)
Dielectric constant 8.6099999999999994
InChI 1S/C4H8S/c1-2-4-5-3-1/h1-4H2
InChIKey RAOIDOHSFRTOEL-UHFFFAOYSA-N
SMILES C1CCSC1
LogP 1.8 at 20℃
CAS DataBase Reference 110-01-0(CAS DataBase Reference)
NIST Chemistry Reference Thiophene, tetrahydro-(110-01-0)
EPA Substance Registry System 110-01-0(EPA Substance)

Safety Data

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H302+H312+H332-H315-H319-H412
Precautionary statements  P210-P273-P280-P301+P312-P303+P361+P353-P304+P340+P312
Hazard Codes  F,Xn
Risk Statements 
R11:Highly Flammable.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/38:Irritating to eyes and skin .
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
Safety Statements 
S16:Keep away from sources of ignition-No smoking .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S36/37:Wear suitable protective clothing and gloves .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
RIDADR  UN 2412 3/PG 2
WGK Germany  2
RTECS  XN0370000
Autoignition Temperature 202 °C
TSCA  Yes
REACH Registrations Active
HazardClass  3
PackingGroup  II
HS Code  29349990
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Aquatic Chronic 3
Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
Safety Profile
Mildly toxic by inhalation. Flammable liquid. Potentially explosive reaction with hydrogen peroxide. When heated to decomposition it emits toxic fumes of SOx.
Hazardous Substances Data 110-01-0(Hazardous Substances Data)
Toxicity
LD50 by inhalation in mice: 26.7 mg/l (Carlucci)

Raw materials And Preparation Products

Hazard Information

Material Safety Data Sheet(MSDS)

Well-known Reagent Company Product Information

Supplier