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网站主页CAS数据库列表 367-29-3更多图谱5-氟-2-甲基苯胺(367-29-3)红外图谱(IR2)

5-氟-2-甲基苯胺

产品名称 5-氟-2-甲基苯胺

CAS号367-29-3

分子式C7H8FN

分子量125.14

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  • Mass

    MS-NW-6619          
    5-fluoro-o-toluidine
    C7H8FN              (Mass of molecular ion:    125)
    

       Source Temperature: 260 °C
       Sample Temperature: 190 °C
       Reservoir, 75 eV
    

          27.0       1.8
          28.0       4.3
          30.0       2.6
          31.0       1.1
          38.0       1.4
          39.0       2.6
          42.0       1.2
          50.0       3.1
          51.0       6.2
          51.5       1.1
          52.0       3.5
          52.5       2.4
          53.0       1.1
          57.0       3.4
          61.0       1.1
          62.0       2.7
          62.5       2.4
          63.0       1.9
          69.0       1.0
          70.0       2.4
          71.0       1.4
          74.0       1.1
          75.0       2.3
          76.0       1.5
          77.0       8.1
          78.0       2.7
          81.0       1.2
          83.0       1.9
          95.0       5.2
          96.0       4.5
          97.0      10.5
          98.0       3.0
         104.0       2.5
         106.0       1.8
         107.0       6.9
         108.0       8.0
         109.0       4.1
         122.0       2.8
         124.0     100.0
         125.0      89.8
         126.0       7.3
    

90 MHz in CDCl3

parameter in CCl4


  • 1H NMR 89.56 MHz
    C7 H8 F N 0.030 g : 0.5 ml CDCl3
    5-fluoro-o-toluidine
    ChemicalStructure
        Assign.     Shift(ppm)
    A 6.93 B 6.38 C 6.36 D 3.61 E 2.093

         Hz     ppm     Int.
    

        629.75   7.032     62
        629.25   7.027     60
        623.31   6.960     67
        622.63   6.953     64
        620.44   6.928    108
        614.69   6.864     73
        614.00   6.856     93
        578.06   6.455    133
        576.00   6.432    143
        573.50   6.404    134
        571.81   6.385    162
        569.38   6.358    148
        565.38   6.313    112
        562.94   6.286    237
        323.00   3.607    278
        187.44   2.093   1000
    


  • 1H NMR 300 MHz
    C7 H8 F N 10 mol% in CCl4
    5-fluoro-o-toluidine
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 6.83 D(B) 6.25 D(C) 6.19 D(D) 2.02 J(A,B) 8.21 J(A,C) 0.29 J(A,D) -0.74 J(A,X) 6.38 J(B,C) 2.64 J(B,D) 0.31 J(B,X) 8.34 J(C,D) 0.43 J(C,X) 10.15 J(D,X) 0.0 D(E) 3.50 AKSNES,D. &.KRONHAUG,F.H. ACTA CHEM.SCAND. 25, 1871 (1971)

         Hz     ppm     Int.
    

       2056.19   6.854     68
       2050.22   6.834     74
       2049.59   6.832     81
       2048.51   6.828     83
       2042.13   6.807     72
       2041.41   6.805     68
       1884.59   6.282     51
       1881.99   6.273     67
       1876.37   6.255     97
       1873.72   6.246    119
       1868.15   6.227     58
       1865.41   6.218     66
       1863.34   6.211    113
       1860.69   6.202     80
       1853.19   6.177    100
       1850.63   6.169     80
       1049.99   3.500   1000
        605.98   2.020    278
    

in CDCl3



KBr disc



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