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网站主页CAS数据库列表 287-27-4更多图谱硫化环丙烷(287-27-4)核磁图(13CNMR)

硫化环丙烷

产品名称 硫化环丙烷

CAS号287-27-4

分子式C3H6S

分子量74.14

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  • Mass

    MS-NW-0986          
    thietane
    C3H6S               (Mass of molecular ion:     74)
    

       Source Temperature: 240 °C
       Sample Temperature: 130 °C
       Reservoir, 75 eV
    

          26.0       2.2
          27.0       4.9
          28.0       2.1
          38.0       1.5
          39.0       8.6
          40.0       1.0
          41.0      10.8
          43.0       1.3
          44.0       1.2
          45.0      20.6
          46.0     100.0
          47.0       6.5
          48.0       4.6
          58.0       1.8
          59.0       2.1
          69.0       1.3
          71.0       1.7
          73.0       3.1
          74.0      63.5
          75.0       2.7
          76.0       3.3
    

90 MHz in CDCl3

parameter neat


  • 1H NMR 89.56 MHz
    C3 H6 S 0.02 ml : 0.5 ml CDCl3
    thietane
    ChemicalStructure
        Assign.     Shift(ppm)
    A 3.234 B 2.972

         Hz     ppm     Int.
    

        303.25   3.386     78
        300.44   3.355    129
        299.38   3.343    148
        297.94   3.327    208
        297.38   3.321    228
        296.31   3.309    161
        293.50   3.278    133
        292.94   3.271    114
        291.00   3.250   1000
        290.38   3.243    364
        289.56   3.234    217
        288.94   3.227    161
        288.25   3.219     93
        285.13   3.184    727
        283.94   3.171    275
        283.00   3.160    274
        281.94   3.149    141
        276.94   3.093    211
        274.56   3.066    199
        272.81   3.047    110
        272.25   3.040     77
        270.31   3.019    341
        268.88   3.003    179
        268.00   2.993     76
        264.94   2.959    127
        264.13   2.950    224
        263.25   2.940    240
        260.88   2.913    178
        260.13   2.905     80
        257.00   2.870    139
        254.25   2.839    109
    


  • 1H NMR 300 MHz
    C3 H6 S neat
    thietane
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 3.214 D(B) 2.943 J(A,A') -8.70 J(A,A'') 1.20 J(A,A''') -0.20 J(A,B) 8.93 J(A,B') 6.27 J(A',A'') -0.20 J(A',A''') 1.20 J(A',B) 6.27 J(A',B') 8.93 J(A'',A''') -8.70 J(A'',B) 8.93 J(A'',B') 6.27 J(A''',B) 6.27 J(A''',B') 8.93 J(B,B') -11.73 LOZAC'H,R. & BRAILLON,B. J.CHIM.PHYS. 67, 340 (1970)

         Hz     ppm     Int.
    

        972.40   3.241    360
        971.72   3.239    379
        964.60   3.215   1000
        961.17   3.204     52
        960.37   3.201     55
        959.71   3.199     55
        957.32   3.191    587
        956.84   3.189    577
        897.84   2.993     94
        896.57   2.989     91
        893.29   2.978     32
        890.20   2.967    258
        888.61   2.962    142
        886.89   2.956     41
        885.65   2.952     27
        882.15   2.940    286
        878.66   2.929     31
        875.63   2.919    135
        874.28   2.914    172
        873.10   2.910     66
        871.44   2.905     14
        867.75   2.892     46
        866.43   2.888     44
    

in CDCl3



liquid film