(R,R)-(-)-N,N'-ビス(3,5-ジ-tert-ブチルサリチリデン)-1,2-シクロヘキサンジアミノマンガン(III)クロリド

外観

黄赤色～褐色粉末～結晶

化学的特性

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE is Dark brown powder or chunks

使用

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE is a coordinated compound of manganese and a salen-type ligand. It is also used as an asymmetric catalyst used to enantioselectively transform prochiral alkenes into epoxides.

反応性

1. Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
2. Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
3. symmetric Kinetic resolution of secondary alcohols in water.
4. Enantioselective Reformatsky reaction with ketones.

一般的な説明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.