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外観
白色～うすい褐色, 結晶～粉末
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溶解性
水に難溶。アルコール, アセトンに可溶。
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用途
樹脂原料、架橋剤
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用途
有機合成中間体、ポリイミド樹脂原料
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化学的特性
Colorless crystalline
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使用
4,4＇-Oxydianiline has been used to produce polyimide resins.
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調製方法
4-Aminophenyl ether was produced in relatively large volume
(on the order of 100,000–1,000,000 lb) in the 1970s but
has since declined significantly. The compound is used
primarily in the production of polyimide and polyesterimide
resins. These resins are used in the manufacture of temperature-
resistant products such as wire enamels, coatings, film,
insulating varnishes, and flame-retardant fibers.
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一般的な説明
Odorless colorless crystals or an odorless fine, beige powder.
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空気と水の反応
Insoluble in water.
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反応プロフィール
4,4'-Oxydianiline oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. A mixture of liquid air and diethyl ether exploded spontaneously [MCA Case History 616(1960)].
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健康ハザード
4-Aminophenyl ether is highly toxic to animals. There is suffi cient evidence as a carcinogenicity and has caused adenomas and carcinomas in the thyroid and liver of experimental rats.
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火災危険
4,4'-Oxydianiline is combustible.
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安全性プロファイル
Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx
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職業ばく露
Intermediate in the manufacture of
high-temperature-resistant, straight polyimide and poly
(esterimide) resins capable of withstanding temperatures of
Up to 480°C for short periods or 260°C for prolonged periods
of time. Some p-phenylenediamine compounds have
been used as rubber components, and DFG warns of danger
of skin sensitization.
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発がん性
4,4′-Oxydianiline is reasonably anticipated to be a human carcinogenbased on sufficient evidence of carcinogenicity from studies in experimental animals.
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輸送方法
UN2811 Toxic solids, organic, n.o.s., Hazard
Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name
Required. UN3077 Environmentally hazardous substances,
solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous
material, Technical Name Required.
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不和合性
Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions.
Keep away from alkaline materials, strong bases,
strong acids, oxoacids, and epoxides. Slowly hydrolyzes in
water, releasing ammonia, and forming acetate salts.
Decomposes at 265C releasing toxic oxides of nitrogen,
sulfur, and carbon. Decomposed by strong ultraviolet light.
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廃棄物の処理
Incineration with provision
for nitrogen oxides removal from flue gases.
