テトラフェニルアルソニウム·クロリド

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H410：長期的影響により水生生物に非常に強い毒性

• 注意書き

  P273：環境への放出を避けること。

テトラフェニルアルソニウム·クロリド 価格

テトラフェニルアルソニウム·クロリド 化学特性,用途語,生産方法

• 化学的特性

  crystalline solid

• 使用

  Cation exchange reagent. Used to prepare arsonium amide, oxime, and carbohydrate derivatives.

• 安全性プロファイル

  Poison by intravenous route. When heated to decomposition it emits toxic fumes of As and Cl-.

• 純化方法

  A neutralised aqueous solution is evaporated to dryness. The residue is extracted into absolute EtOH, evaporated to a small volume and precipitated by addition of absolute Et2O. It is again dissolved in a small volume of absolute EtOH or ethyl acetate and re-precipitated with Et2O. Alternatively, it is purified by adding conc HCl to precipitate the chloride dihydrate. Redissolve in water, neutralise with Na2CO3 and evaporate to dryness. The residue is extracted with CHCl3 and finally crystallised from CH2Cl2 or EtOH by adding Et2O. If the aqueous layer is somewhat turbid treat. it with Celite and filter through filter paper. It can be dehydrated before use in a vacuum. The tetrafluoroborate salt has m 293-295o (needles from MeCN), and the picrate salt has m 203-204o (from EtOH). [Blicke et al. J Am Chem Soc 57 702 1935, Duke & Brown J Am Chem Soc 76 1443 1954, Popov & Humphrey J Am Chem Soc 81 2043 1959, Singhal & Raj Synth Inorg Met-org Chem 23 1011 1993, Beilstein 16 III 1006, 16 IV 1170.] POISONOUS.

テトラフェニルアルソニウム·クロリド 生産企業

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テトラフェニルアルソニウム·クロリド スペクトルデータ(¹HNMR、IR1、IR2、MS、Raman)

507-28-8, テトラフェニルアルソニウム·クロリド キーワード