ジクロロオキソジルコニウム(IV)

化学名:ジクロロオキソジルコニウム(IV)

CAS番号.7699-43-6

英語名:Zirconium oxychloride

CBNumberCB6470074

MFCl2OZr

MW178.13

MOL File7699-43-6.mol

别名

ジルコニウム(IV)オキシドジクロリド

オキシ塩化ジルコニウム

オキソジルコニウム(IV)ジクロリド

ジクロロオキソジルコニウム(IV)物理性質

融点	−15 °C
比重(密度)	1.344 g/mL at 25 °C
溶解性	soluble in H2O, ethanol
外見	液体
色	無色透明
Merck	13,10237
安定性：	安定。強力な酸化剤、水、湿気、アルカリ金属とは相容れない。
CAS データベース	7699-43-6(CAS DataBase Reference)
EPAの化学物質情報	Zirconium, dichlorooxo- (7699-43-6)

安全性情報

主な危険性	C,Xn
Rフレーズ	23-34-37-20/21/22-36/38
Sフレーズ	26-36-45-36/37/39-36/37
RIDADR	UN 1789
WGK Germany	1
国連危険物分類	8
容器等級	III
有毒物質データの	7699-43-6(Hazardous Substances Data)
化審法	優先評価化学物質
PRTR法	第1種指定化学物質

危険有害性情報のコード(GHS)

ジクロロオキソジルコニウム(IV) 価格

製品番号	包装	価格	製品説明	購入
Sigma-Aldrich Japan 464198	250ml	￥7290	ジルコニルクロリド溶液 30% in hydrochloric acid	購入

MSDS Information

ジクロロオキソジルコニウム(IV) 化学特性,用途語,生産方法

用途
ジルコニル石けん?レーキ顔料原料、触媒 (化学工業日報社)
化学的特性
Zirconium oxychloride exists as white silky crystals, soluble in water and alcohol. With water, the octahydrate is formed as tetragonal white needles. It is extremely hygroscopic and decomposes to zirconium tetrachloride (ZrCl4) and zirconium oxide (ZrO2) at 250 C. It is also formed as the octahydrate [13520-92-8] as white, tetrahedral crystals that are very soluble in water, ethyl alcohol, ether, and methanol, among others, but only slightly soluble in hydrochloric acid. When heated to decomposition, it emits toxic fumes of hydrogen chloride.
使用
Textile, cosmetic and grease additive, antiperspirant, water repellents, chemical reagent, zirconium salts, in lakes and toners of acidic and basic dyes, oil-field acidizing aid.
反応プロフィール
Acidic salts, such as Zirconium oxychloride, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
健康ハザード
Has only a mild pharmacological action. Inhalation of dust may irritate nose and throat. Contact with eyes or skin causes irritation.
安全性プロファイル
Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits toxic fumes of Cl-. Used as an antiperspirant. See also ZIRCONIUM COMPOUNDS and CHLORIDES.
純化方法
Crystallise it repeatedly from 8M HCl to give ZrOCl2.8H2O (see below). On drying, ZrOCl2.6H2O, m 150o, is formed. The product is not free from hafnium. [Blumenthal J Chem Ed 39 607 1962.]

ジクロロオキソジルコニウム(IV) 上流と下流の製品情報

ジクロロオキソジルコニウム(IV) 生産企業

7699-43-6, ジクロロオキソジルコニウム(IV) キーワード

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